Electrochemical impedance spectroscopy (EIS) and scanning Kelvin probe (SKP) were used to study the failure of the coating modified with air-plasma treatment in 3.5 % mass fraction of NaCl. The results show that the failure process can be divided into three stages including water penetration, accumulation of corrosion products at the location of a defect, water penetration of the entire coating and coating failure. The EIS results show that the plasma-treated samples exhibit an additional electrical double-layer capacitor that delays the coating failure during the second stage. The potential of the non-plasma-treated samples decrease faster than that of the plasma-treated samples according to the SKP study. As the transition layer, air plasma delays the coating failure due to the chemical bond between the metal substrate and the coating. Keywords: air-plasma treatment, electrochemical impedance spectroscopy, scanning Kelvin probe, coating failure, hydrostatic pressure Elektrokemijsko impedan~no spektroskopijo (angl. EIS) in vrsti~no Kelvinovo sondo (SKP) smo uporabili za preu~evanje po{kodb na prevleki, modificirani s plazmo, v 3,5 mas. % raztopini NaCl. Rezultati ka`ejo, da se nastajanje po{kodb lahko razdeli na tri faze, vklju~no s penetracijo vode: na akumulacijo korozijskih produktov na mestu napake, na prodiranje vode v dele celotne prevleke in na odpoved prevleke. Rezultati EIS ka`ejo, da imajo vzorci, obdelani v plazmi, dodaten elektri~ni dvoslojni kondenzator, ki v drugi fazi upo~asni po{kodbo prevleke (premaza). SKP-analize so pokazale, da se potencial plazemsko neobdelanih vzorcev zmanj{uje hitreje kot tistih vzorcev, ki so bili obdelani s plazmo. Kot prehodna plast, obdelava z zra~no plazmo upo~asni po{kodbo premaza zaradi kemijske vezi med kovinskim substratom in prevleko. Klju~ne besede: obdelava s plazmo, elektrokemijska impedan~na spektroskopija, skeniranje s sondo Kelvin, odpoved prevleke, hidrostati~ni tlak
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.