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tive of the XPS spectrum and the low-energy region of the APS threshold over which effects due to the core-level width are expected to dominate. This close agreement strongly suggests that identical initial (core) energy states are involved for both XPS and APS in this case. However, as a result of the increasing predominance of finalstate effects on the high-energy side of the APS threshold, there is no obvious correspondence between features in APS and the peak in the XPS core-level density of states from which the "binding energy" is usually determined.
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