Metal complexes of the Schiff base ligand, synthesized via condensation p-dimethylamino benzaldehyde with Bis (4-aminoantipyrine) benzene 1, 4-diamine which has synthesized from condensation 1, 4-phenylene diamine and 4-aminoantipyrine, are synthesized from chloride salts of Co (II) and Ni(II) with ligand in ethanol. The metal complexes and ligand are characterized on the basis of elemental analyses, melting point, molar conductance, UV –Visible, FTIR and thermogravimetric analysis. The molar conductance data reveal that the metal chelates of the ligand with Co (II) and Ni (II) are electrolytes. The present results suggested that the Schiff base ligand as tetradentate is coordinated with metal ions through the four nitrogen atoms.

The polymers derived from heterocyclic rings like imidazole was prepared and supported to produce catalytic active supported catalyst. This catalyst was characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), H NMR and UV-visible spectroscopy. The catalyst showed high catalytic activity in the oxidation of cyclohexene and cyclopentene under optimized conditions. In this work cyclohexene and cyclopentene were selected as model alkene for determination the capacity of the prepared imidazole polymer catalyst under optimized conditions of temperature and time of reaction. The catalyst could be readily separated from the catalytic system using uploading 3-5 milligrams of Copper(II), Nickel(II) and Cobalte(II) ions with the surface of polymer the conversion them to nano-particle which are identified by x-ray diffraction. For this research, a statistical method called Response Surface Methodology (RSM) has been used to economize the number of experiments and their meaningful interpretation. The effect of metallated polymer with Copper(II), Nickel(II) and Cobalte(II) were taken to increase the efficiency of oxidation. Optimization results for 0.33 mmole cyclohexene and cyclopentene showed that maximum oxidation efficiency 90. % was achieved at the optimum conditions: catalyst amount 350 mg, temperature 70.0, time 3.30 h and oxidant= 5.25 m mole.

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