An overview on magnetic of nanostructured magnetic materials is presented, with particular emphasis on the basic features displayed by granular nanomagnetic solids. Besides a review of the basic concepts and experimental techniques, the role of structural disorder (mainly the distribution of grain sizes), interparticle magnetic interactions and surface effects are also discussed with some detail. Recent results, models and trends on the area are also discussed.
The anhysteretic magnetization of the granular metallic alloy Cu 90 Co 10 is experimentally studied over a wide temperature range ͑2-700 K͒. The measurements definitely exclude that this alloy is a simple superparamagnet, even in the high-temperature limit, although some features of granular systems ͓such as the typical Langevin-like form of the anhysteretic magnetization curves M (H)͔ are often taken as evidence of superparamagnetism. A phenomenological theory is proposed, explicitly considering that particle moments interact through long-ranged dipolar random forces, whose effect is pictured in terms of a temperature T*, adding to the actual temperature T in the denominator of the Langevin function argument. This simple formula explains all features of the experimental M (H) curves. The theory indicates that the actual magnetic moments on interacting Co particles are systematically larger than those obtained fitting the magnetic data to a conventional Langevin function. The Cu 90 Co 10 granular alloy is therefore identified as an ''interacting superparamagnet'' ISP. The ISP regime appears as separating the high-temperature, conventional superparamagnetic phase from the low-temperature, blocked-particle regime. In this way, a magnetic-regime diagram can be drawn for each granular system. The competition between single-particle and collective blocking mechanisms is briefly analyzed. The proposed interpretation is thought to be applicable to other fine particle systems; its main features and intrinsic limits are discussed.
Spherical magnetic nanoparticles with narrow size distribution and organic capping were diluted in paraffin with different concentrations to verify the role of dipolar interactions on the macroscopic magnetic behavior. Increasing concentration of magnetic nanoparticles leads to higher blocking temperatures. The experimental data were analyzed by means of a recently proposed model that takes into account magnetic interactions of dipolar origin, and an excellent agreement was found. Considering the magnetic interaction among particles it was possible to obtain the real magnetic moment and estimate structural parameters that are consistent with the ones obtained by small angle x-ray scattering and transmission electron microscopy.
The magnetic properties of Cu97Co3 and Cu90Co10 granular alloys were measured over a wide temperature range (2 to 300 K). The measurements show an unusual temperature dependence of the coercive field. A generalized model is proposed and explains well the experimental behavior over a wide temperature range. The coexistence of blocked and unblocked particles for a given temperature rises difficulties that are solved here by introducing a temperature dependent blocking temperature. An empirical factor gamma (γ) arise from the model and is directly related to the particle interactions. The proposed generalized model describes well the experimental results and can be applied to other single-domain particle system.
This work focuses on synthetic methods to produce monodisperse Ni colloidal nanoparticles (NPs), in the 4-16 nm size range, and their structural characterization. Narrow size distribution nanoparticles were obtained by high-temperature reduction of a nickel salt and the production of tunable sizes of the Ni NPs was improved compared to other methods previously described. The as-synthesized nanoparticles exhibited spherical shape and highly disordered structure, as it could be assigned by X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). Annealing at high temperature in organic solvent resulted in an increase of nanoparticle atomic ordering; in this case, the XRD pattern showed an fcc-like structure. Complementary data obtained by X-ray absorption spectroscopy confirmed the complex structure of these nanoparticles. Temperature dependence of the magnetic susceptibility of these highly disordered Ni NPs showed the magnetic behavior cannot be described by the conventional superparamagnetic theory, claiming the importance of the internal structure in the magnetic behavior of such nanomaterials.
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