A. General 47 1. Condensation of data 47 2. Units 47 3. Description of drift 48 B. Vibrating-Sample Magnetometer Data 49 lo Pure erbium 49 2* 5^-^7 5 3» 1»% 5 Er^ g 53 5 » LUggErgo 5, 6. T:75Ek25 5° 7. Lu^gErgg 57 8. Need for zero field measurements 5/ l:li Rifi'-j C. Mutual Inductance Bridge Data ')'j V. DISCUSSION A. Magnetic Results lo Pure erbium 2. Alloys B.
Carefully analyzed splierical cinclc crystal riamplex wore prepared oL' orbiiiiu and of alloyy whose approximate compositions were: , Y^oEr,;^. Y?Er-^ , LUo-jEr^^, Lu^oEr^o, and. Ma^pietie measureraerits were made on each ol' these samples along the tt'iroc principle crystallographic axes in the range 1.2 to gOO^K and applied fields up to K-Oe. For pure erhiim, the saturation moment along the c-axis was found to be 270.O ±2.0 emu/g. by fitting the data to a plot and extrapolating to 0°K. This is to be compared with a theoretical value of 3OO.5 emu/g. The discrepancy between experiment and theory is apparently the result of a ferromagnetic spiral arrangement of spins where the spins are cocked at an angle to the c-axis rather than being aligned parallel to it. Curie and N^el temperatures were found at l8.2 ±0.5 and 86.5 ±0.5°K respectively. Peaks in the c-axis moment vs. temperature curves were also observed which extrapolated to zero-field temperatures of 28.0 ±0.5 and 50.5 ±0.5°K. The latter corresponds to the transition from one antiferromagnetic structure to another while the significance of the former is unknown. Peaks occurred in both the a-and b-axis moment vs. temperature curves below about 18.5 K-Oe. Below about 10 X-Oe., the temperature of the peaks was field independent and occurred at about l8.2°K. In both the a-and b-axis moment vs. field curves, there were discontinuous increases in moment at about 18.5 K-Oeo near 4.2°K. These apparently correspond to a sudden transition to a nearly parallel alignment of spins at an angle of about 23° to the c-axis. Some very small basal-plane anisotropy was observed below 40°K. At 4.2°X, the b-axis moment was about 2% larger at .high V rie Id:: " None or I,lie alloyt; ;;i,uii.ic:d wore i'crromfinotic in zrjro l'i'tld. 'I'ha l.timprrattircr, of thn alloyri ware proportional to thr: %/% jkw. t oT th'.; _2 avcra}:c do Gennos factor, = AG''\ The constant, A, warj found to bo '19.0 for tlio yttriiun-crbium alloys and 53*5 for the lutetium-erbium alloys. An anomalouiî peak was observed in the c-axis moment vs. temperature curves for two alloys, LuggEr^g and YgoErgg. In both alloys, the peak vfas not observed at fields less than about 6 K-Oe. However, by extrapolating to zero field, the temperatures of the peaks were determined to be 27-5 ±1.0 and 17•5 ±1.0°K respectively for the two alloys. In addition to these • anomalies, a peak was observed at 29.0 ±0.5°K for a polycrystalline YggEryg alloy by a zero-field mutual-induetance bridge technique. These peaks are evidently due to a transition between two different magnetic structures, but whether they correspond to the structure change observed by Child _et in yttrium-erbium alloys is not known. Peaks occurred in both the a-and b-axis moment vs. temperature curves for the YssEr^g, LugsEr^s, YgoErgo, and LUgoErso alloys at l6.4, I6.I, 12.5, and about 9.0°K respectively. These peaks are apparently related to the l8.0°K basal-plane peak in pure erbium. This peak corresponds to the ferromagnetic-antiferromagnetic transition in p...
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