Two ferrocene-isocyanide ligands, 1-isocyanoferrocene (FcNC) and 1,1’-diisocyanoferrocene [Fc(NC)2], were observed to react with the redox active iron-thiolate core complexes [(CpFe)2(μ-SEt)2(CH3CN)2][BF4]2 (1[BF4]2) to form the respective ferrocenyl-isocyanide adducts, [(CpFe)2(μ-SEt)2(FcNC)2][BF4]2 (2[BF4]2) and...
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