Through the esteri cation of cellulose (Cell) with ethylenediaminetetraacetic dianhydride, ethylenediaminetetraacetic acid-functionalized cellulose (Cell-EDTA) was conveniently obtained. Furtherly a novel and e cient Cell-EDTA-supported palladium catalyst (Pd@Cell-EDTA) was easily prepared via coordination of Cell-EDTA with PdCl 2 . The as-prepared Pd@Cell-EDTA was fully characterized by inductively coupled plasma atomic emission spectrometry (ICP-AES), X-ray photoelectron spectroscopy (XPS), Flourier transform infrared spectra (FTIR), energy-dispersive spectroscopy (EDS), scanning electron microscopy, transmission electron microscopy (SEM), thermogravimetric analysis (TGA) and derivative thermogravimetric analysis (DTG) techniques. Then Pd@Cell-EDTA were successfully exerted as catalysts in Suzuki reactions and Sonogashira reactions. Due to the interactions of carboxylic groups, nitrogen atoms, and hydroxyl groups on cellulose, the Pd complex showed excellent activity towards these carbon-carbon cross-coupling reactions. The catalyst recycling experiment for Suzuki model reaction showed that the catalyst can be reused at least ve times without signi cant losing its catalytic performance. The present cellulose-based Pd@Cell-EDTA catalyst offers the salient features of wide application, excellent catalytic activity, good reusability, tolerance of broad scope of substrate, and environmental benign.

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Through the esterification of cellulose (Cell) with ethylenediaminetetraacetic dianhydride, ethylenediaminetetraacetic acid-functionalized cellulose (Cell-EDTA) was conveniently obtained. Furtherly a novel and efficient Cell-EDTA-supported palladium catalyst (Pd@Cell-EDTA) was easily prepared via coordination of Cell-EDTA with PdCl2. The as-prepared Pd@Cell-EDTA was fully characterized by inductively coupled plasma atomic emission spectrometry (ICP-AES), X-ray photoelectron spectroscopy (XPS), Flourier transform infrared spectra (FTIR), energy-dispersive spectroscopy (EDS), scanning electron microscopy, transmission electron microscopy (SEM), thermogravimetric analysis (TGA) and derivative thermogravimetric analysis (DTG) techniques. Then Pd@Cell-EDTA were successfully exerted as catalysts in Suzuki reactions and Sonogashira reactions. Due to the interactions of carboxylic groups, nitrogen atoms, and hydroxyl groups on cellulose, the Pd complex showed excellent activity towards these carbon-carbon cross-coupling reactions. The catalyst recycling experiment for Suzuki model reaction showed that the catalyst can be reused at least five times without significant losing its catalytic performance. The present cellulose-based Pd@Cell-EDTA catalyst offers the salient features of wide application, excellent catalytic activity, good reusability, tolerance of broad scope of substrate, and environmental benign.