In this paper, highly correlated <i>ab initio</i> calculations are performed for accurately determining the electronic structures and spectroscopic features of the Λ-S and Ω low-lying electronic states of SbS . The potential energy curves for 27 Λ-S states of the first three dissociation asymptotes are constructed. Spectroscopic constants and vibrational states for all bound states are well determined. The calculated atomic states for both atoms are consistent with experimental data quite well. Several low-lying Ω electronic states are also investigated, and their respective spectroscopic constants and vibrational states are obtained and compared with those of corresponding Λ-S states, which indicates that the spin-orbit coupling effect gives rise to a minor influence on the electronic states of SbS. To verify our computational accuracy, the additional calculations for the low-lying electronic states of PS, AsS and BiS are also carried out. Our derived results are in reasonable agreement with available experimental data. In addition, vibrational spectra from the excited Ω states to the ground state of SbS are simulated, including bands of X(3/2)→X(1/2), 2(1/2)→X(1/2), 4(1/2)→X(1/2), 5(1/2)→X(1/2) and 6(1/2)→X(1/2). The X(3/2)→X(1/2) band is found in the mid-infrared region, while the others are located in the visible region. The predictive results provided in this paper are expected to serve as a guideline for further researches, such as assisting laboratorial detections and analyzing observed spectrum of SbS.
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