Dynamic controllability of self‐organized helical superstructures in spatial dimensions is a key step to promote bottom‐up artificial nanoarchitectures and functional devices for diverse applications in a variety of areas. Here, a light‐driven chiral overcrowded alkene molecular motor with rod‐like substituent is designed and synthesized, and its thermal isomerization reaction exhibits an increasing structural entropy effect on chemical kinetic analysis in anisotropic achiral liquid crystal host than that in isotropic organic liquid. Interestingly, the stimuli‐directed angular orientation motion of helical axes in the self‐organized helical superstructures doped with the chiral motors enables the dynamic reconfiguration between the planar (thermostationary) and focal conic (photostationary) states. The reversible micromorphology deformation processes are compatible with the free energy fluctuation of self‐organized helical superstructures and the chemical kinetics of chiral motors under different conditions. Furthermore, stimuli‐directed reversible nonmechanical beam steering is achieved in dynamic hidden periodic photopatterns with reconfigurable attributes prerecorded with a corresponding photomask and photoinduced polymerization.
We have observed P-Cygni and asymmetric, blue-shifted absorption profiles in the He I λ10830 lines of twelve R Coronae Borealis (RCB) stars over short (1 month) and long (3 year) timescales to look for variations linked to their dust-formation episodes. In almost all cases, the strengths and terminal velocities of the line vary significantly and are correlated with dust formation events. Strong absorption features with blue-shifted velocities ∼400 km s −1 appear during declines in visible brightness and persist for about 100 days after recovery to maximum brightness. Small residual winds of somewhat lower velocity are present outside of the decline and recovery periods. The correlations support models in which recently formed dust near the star is propelled outward at high speed by radiation pressure and drags the gas along with it.
A photo-responsive macroscopic switch was fabricated using a chiral azo-calix[4]arene derivative (FC4AD) functionalized silicon surface and exhibited selective and reversible recognition of (1R,2S)-1-amino-2-indanol through the variation of wettability. This photo-responsive device may have wide applications in controlled release of chiral drugs and in biosensors.
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