Hydrodeoxygenation
(HDO) of bio-oil derived from liquefaction of
a palm empty fruit bunch (EFB) in glycerol was investigated. To enhance
the heating value and reduce the oxygen content of upgraded bio-oil,
hydrodeoxygenation of light bio-oil over Ni- and Co-based catalysts
on an Al2O3 support was performed in a rotating-bed
reactor. Two consecutive steps were conducted to produce bio-oil from
EFB including (1) microwave-assisted wet torrefaction of EFB and (2)
solvothermolysis liquefaction of treated EFB in a Na2CO3/glycerol system. The HDO of as-prepared bio-oil was subsequently
performed in a unique design reactor possessing a rotating catalyst
bed for efficient interaction of a catalyst with bio-oil and facile
separation of the catalyst from upgraded bio-oil after the reaction.
The reaction was carried out in the presence of each mono- or bimetallic
catalyst, namely, Co/Al2O3, Ni/Al2O3, NiMo/Al2O3, and CoMo/Al2O3, packed in the rotating-mesh host with a rotation
speed of 250 rpm and kept at 300 and 350 °C, 2 MPa hydrogen for
1 h. From the results, the qualities of upgraded bio-oil were substantially
improved for all catalysts tested in terms of oxygen reduction and
increased high heating value (HHV). Particularly, the NiMo/Al2O3 catalyst exhibited the most promising catalyst,
providing favorable bio-oil yield and HHV. Remarkably greater energy
ratios and carbon recovery together with high H/O, C/O, and H/C ratios
were additionally achieved from the NiMo/Al2O3 catalyst compared with other catalysts. Cyclopentanone and cyclopentene
were the main olefins found in hydrodeoxygenated bio-oil derived from
liquefied EFB. It was observed that cyclopentene was first generated
and subsequently converted to cyclopentanone under the hydrogenation
reaction. These compounds can be further used as a building block
in the synthesis of jet-fuel range cycloalkanes.
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