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Engineered nanomaterials alone or in combination with other technologies may improve in situ subsurface remediation of legacy and emerging contaminants.

Based on the characteristics of shallow buried, non-trap structure and close cover, non-diagenesis, weak cementation and easy fragmentation of natural gas hydrate deposits in China, a solid fluidization well testing and production scheme to develop these kind of natural gas hydrate is proposed. The main idea is to transfer the non-diagenetic natural gas hydrate sediments buried in shallow layer of deep-water into a closed multi-phase transporting and lifting system through mechanical crushing fluidization, during the lifting riser system from seabed to surface, hydrate will be dissociated gradually based natural rule of sea water temperature rising and the hydrostatic pressure decrease with the change of water depth during the lifting process, to turn the uncontrollable decomposition process of non-diagenetic hydrate into controllable, and to achieve safe field exploitation of natural gas hydrate in the surface and shallow layer of deep-water. After the validity was verified by the laboratory experimental study, CNOOC successfully implemented the world's first solid fluidization well testing and production of marine non-diagenetic hydrate with the water depth of 1310m and the hydrate sediments layers 117~196m depth in May 2017. It means China has found an innovation way about natural gas hydrate exploration and development with self-developed key technology and tools. The implementation relied on the Deepwater Engineering & Survey Vessel "HYSY708" at the station of Li Wan 3 in the South China Sea and it was supported by fully self-developed technology, process and facilities.

The solid-gas coupling model for mining coal-rock mass deformation and pressure relief gas flow in protection layer mining is the key to determine deformation of coal-rock mass and migration law of pressure relief gas of protection layer mining in outburst coal seams. Based on the physical coupling process between coal-rock mass deformation and pressure-relief gas migration, the coupling variable of mining coal-rock mass, a part of governing equations of gas seepage field and deformation field in mining coal-rock mass, is introduced. Then, a new solid-gas coupling mathematical model reflecting the coupling effects of gas adsorption/desorption, gas pressure, and coal-rock mass deformation on the mining coal-rock mass deformation and pressure relief gas flow is established combined with the corresponding definite conditions. It lays a theoretical foundation for the numerical calculation of the deformation of mining coal-rock mass and the migration law of gas under pressure relief in the outburst coal seam group.

Chlorite and serpentine are common magnesium-containing gangue minerals in copper sulfide flotation. In this study, sodium alginate, a natural hydrophilic polysaccharide, was introduced as a selective depressant for these gangue minerals. Micro-flotation tests were conducted on both single minerals and synthetic mixtures. The flotation results showed that sodium alginate could simultaneously depress the flotation of chlorite and serpentine effectively, but seldom influenced the floatability of chalcopyrite at pH 9. In the ternary mixture flotation, a concentrate with a Cu grade of 31% could be achieved at Cu recovery of 90%. The selective depression of chlorite and serpentine was also validated by the real ore flotation experiments. The selective depression mechanism was investigated through adsorption tests, zeta potential measurements, and FTIR analyses. The adsorption density results implied that sodium alginate selectively adsorbed on the surface of phyllosilicates, but no adsorption on the chalcopyrite surface was observed. The zeta potential results showed that the sodium alginate could selectively decrease the surface charge of chlorite and serpentine. The FTIR results revealed the chemical adsorption of sodium alginate on the chlorite and serpentine surface and no form of adsorption on chalcopyrite, agreeing well with the adsorption density results. On the basis of these results, a selective adsorption model of sodium alginate on the mineral surface was proposed.