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The rapidly growing technological demand for lithium-ion batteries has prompted the development of novel cathode materials with high energy density, low cost, and improved safety. High voltage spinel, LiNi 0.5 Mn 1.5 O 4 (LNMO), is one of the most promising candidates yet to be commercialized. The two primary obstacles for this material are the inferior electronic conductivity and fast capacity degradation in full cells due to the high operating voltage. By systematically addressing these limitations, we successfully develop a thick LNMO electrode with areal capacity loadings up to 3 mAh⋅cm À 2. The optimized thick electrode is paired with a commercial graphite anode at both the coin cell and pouch cell level, achieving a full cell capacity retention as high as 72% and 78%, respectively, after 300 cycles. We attribute this superior cycling stability to careful optimizations of cell components and testing conditions, with a specific focus improving electronic conductivity and high voltage compatibility. These results suggest precise control of materials quality, electrode architecture and electrolyte optimization can soon support the development of a cobalt-free battery system based on a thick LNMO cathode (>4 mAh⋅cm 2), which will eventually meet the needs of next-generation Li-ion batteries with reduced cost, improved safety, and assured sustainability.

An acoustic emission technique was used to monitor the cracking behavior and fracture process of thermal barrier coatings subjected to tensile loading. Acoustic emission signals were extracted and preformed by fast Fourier transform, and their characteristic frequency spectrums and dominant bands were obtained to reveal fracture modes. Three different characteristic frequency bands were confirmed, corresponding to substrate deformation, surface vertical cracking and interface delamination, with the aid of scanning electronic microscopy observations. A map of the tensile failure mechanism of air plasma-sprayed thermal barrier coatings was HighlightsWe established several good correlations between AE data and fracture modes.The correlations can be utilized to reveal cracking profile and coating failure.A tensile failure mechanism of coating system was established.Fracture strength of thermal barrier coating has been obtained by this method.The method has a large advantage to study the failure of coating/film materials.

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