Recent advances achieved in triboelectric nanogenerators (TENG) focus on boosting power generation and conversion efficiency. Nevertheless, obstacles concerning economical and biocompatible utilization of TENGs continue to prevail. Being an abundant natural biopolymer from marine crustacean shells, chitosan enables exciting opportunities for low-cost, biodegradable TENG applications in related fields. Here, the development of biodegradable and flexible TENGs based on chitosan is presented for the first time. The physical and chemical properties of the chitosan nanocomposites are systematically studied and engineered for optimized triboelectric power generation, transforming the otherwise wasted natural materials into functional energy devices. The feasibility of laser processing of constituent materials is further explored for the first time for engineering the TENG performance. The laser treatment of biopolymer films offers a potentially promising scheme for surface engineering in polymer-based TENGs. The chitosan-based TENGs present efficient energy conversion performance and tunable biodegradation rate. Such a new class of TENGs derived from natural biomaterials may pave the way toward the economically viable and ecologically friendly production of flexible TENGs for self-powered nanosystems in biomedical and environmental applications.
Kevlar® KM2 fiber is a transversely isotropic material. Its tensile stress-strain response in the axial direction is linear and elastic until failure. However, the overall deformation in the transverse directions is nonlinear and nonelastic, although it can be treated linearly and elastically in infinitesimal strain range. For a linear, elastic, and transversely isotropic material, five material constants are needed to describe its stress-strain response. In this paper, stress-strain behavior obtained from experiments on a single Kevlar KM2 fiber are presented and discussed. The effects of loading rate and the influence of axial loading on transverse and transverse loading on axial stress-strain responses are also discussed.
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