Nanoparticle chain aggregates are used as reinforcing fillers in elastomers (rubber) and significantly enhance the mechanical properties (tensile strength, Young's modulus) of elastomers. Insight into mechanisms of the performance of nanoparticle chain aggregates can be obtained from force vs displacement (force spectroscopy) measurements made with an AFM tip and an aggregate-coated substrate. Distinctive sawtooth patterns were observed which were interpreted as aggregate stretching and breaking events. Based on the measurements, estimates of the aggregate nanomechanical properties were made.
Mechanical properties of nanoparticle chain aggregates (NCA) including tensile strength and Young's modulus were measured using an instrument incorporating an AFM tip under SEM imaging. The NCA were studied individually and as network films. Carbon NCA were made by laser ablation of graphite, and SnO2 NCA were made by oxidation of a tin compound. The films were deformable and showed elastic behavior. NCA serve as reinforcing fillers in rubber and films of SnO2 NCA for trace gas detection.
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