Superhydrophobic and superoleophilic graphene-based sponges are demonstrated as efficient absorbents for a broad range of oils and organic solvents with high selectivity, good recyclability, and excellent absorption capacities up to 165 times their own weight. The findings show promise for large-scale removal of organic contaminants, especially in the field of oil spillage cleanup.
A unified method based on the inclusion formulation is proposed to determine the magnetic, electric, and elastic fields in a composite with piezoelectric and piezomagnetic phases. The composite reinforcements are treated as ellipsoidal inclusions that enable the reinforcement geometries ranging from thin flakes to continuous fibers. Utilizing the proposed method, the magneto-electro-elastic tensors analogous to Eshelby tensors for elastic ellipsoidal inclusions are obtained. With these tensors, the magnetic, electric, and elastic fields around the inclusion as well as concentration factors are determined. Furthermore, based upon the Mori–Tanaka mean-field theory [Acta Metall. 21, 571 (1973)] to account for the interaction between inclusions and matrix, the effective magneto-electro-elastic constants (elastic moduli, piezoelectric coefficients, dielectric constants, piezomagnetic coefficients, magnetoelectric, and magnetic permeability) of the composites are expressed explicitly in terms of phase properties, volume fraction, and inhomogeneity shape. The numerical examinations have been conducted for the three-dimensional BaTiO3–CoFe2O4 composite, and the overall composite behavior has been examined numerically. It is found that the composite reveals interesting magnetoelectric coupling which is absent in each constituent.
After curing, phenol-formaldehyde resins were postcured at 230°C in air for 32 h and then carbonized and graphitized from 300 to 2400°C. Thermal fragmentation and condensation of the polymer structure occurred above 300°C. The crystal size of the cured phenolic resins decreased with the temperature increase. Above 600°C the original resin structures disappeared completely. Below 1000°C the stack size (L c ) and crystal size (L a ) were small. Above 1000°C the L c increased with the increasing treatment temperature. The carbonized and graphitized resins were characterized using Raman spectroscopy. Below 400°C there were no carbon structures in the Raman spectra analysis. Above 500°C the G and D bands appeared. The frequency of the G band of all carbonized and graphitized samples shifted to 1600 cm Ϫ1 from the 1582 cm Ϫ1 of graphite. The D band shifted to 1330 cm Ϫ1 from the 1357 cm Ϫ1 of the imperfect carbon. The carbonized and graphitized phenolic resins could not be considered as truly glassy or amorphous carbon materials because they had some degree of order in the basal plane. However, the crystal size was very small even at 2400°C.
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