A suitable arrangement of the ligand charge can complement a low symmetry system and induce an excellent unexpected SMM behavior.

For the better utilization of solar light and complete oxidation of environmental organic pollutants, it is desired to develop small band gap semiconductors with a deep valence band as efficient visible light photocatalysts. In this work, we prepared the fluorinated Bi2O3 catalysts using a precipitation method, followed by a solvothermal process in the presence of NH4F. The fluorinated Bi2O3 catalysts, especially with the atomic ratio of F to Bi (R F) at 0.2, exhibit much higher photocatalytic activities than the pure Bi2O3 for the degradation of methyl orange (MO) under the visible light irradiation. The effects of the fluorination on the phase structure, special surface areas, morphologies, optical properties, surface-adsorbed species, and electronic band structure of the Bi2O3 were investigated in detail. It was revealed that both the surface-adsorbed and lattice-substituted fluorine, induced by the fluorination to Bi2O3, play critical roles in the enhanced photocatalytic performance of the fluorinated Bi2O3. The two types of fluorine species effectively inhibit the recombination of the photoexcited electron–hole pairs by withdrawing the photoexcited electrons and increase the oxidation power of the photoexcited hole by lowering the valence band edge, respectively.

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