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Shape-memory polymers (SMPs) are synthesized with adjustable glass transition temperature (T g ) ranging from 299 to 322 °C, higher than those reported previously. The polyimide containing thermal stable but flexible linkages within the backbone act as reversible phase, and high molecular weight (M n ) is necessary to form physical cross-links as fixed phase of thermoplastic shape-memory polyimide. The critical M n is 21.3 kg/mol, and the relationship between M n and T g is explored. Thermoset polyimides show higher storage modulus and better shape-memory effects than thermoplastic counterparts due to covalent cross-linking, and the effective cross-link density with the influence on their physical properties is studied. The mechanism of high-temperature shape-memory effect of polyimide on the basis of chain flexibility, molecular weight, and cross-link density is proposed, which will benefit further research on high-temperature SMPs.

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The photothermal effect is applied in CO hydrogenation to reduce the reaction temperature under illumination by encapsulating Pt nanocubes and Au nanocages into a zeolitic imidazolate framework (ZIF-8). Under illumination, the heat generated by the photothermal effect of Au nanocages is mainly insulated in the ZIF-8 to form a localized high-temperature region, thereby improving the catalytic activity of Pt nanocubes.