The Gram matrix of a set of quantum pure states plays key roles in quantum information theory. It has been highlighted that the Gram matrix of a pure-state ensemble can be viewed as a quantum state, and the quantumness of a pure-state ensemble can thus be quantified by the coherence of the Gram matrix [Europhys. Lett. 134 30003]. Instead of the l 1 -norm of coherence and the relative entropy of coherence, we utilize the generalized α-z-relative Rényi entropy of coherence of the Gram matrix to quantify the quantumness of a pure-state ensemble and explore its properties. We show the usefulness of this quantifier by calculating the quantumness of six important pure-state ensembles. Furthermore, we compare our quantumness with other existing ones and show their features as well as orderings.

The Gram matrix of an ensemble of pure states can be regarded as a quantum state, and the quantumness of the ensemble can be quantified by the coherence of the Gram matrix. By using the affinity between mixed states, the concept of Gram matrix of pure-state ensembles can be extended to the one of mixed-state ensembles. By utilizing the generalized α-z-relative Rényi entropy of coherence of Gram matrices, we present a new quantifier of quantumness of mixed-sate ensembles and further reveal its peculiar properties. To illustrate our quantumness of mixed-sate ensembles, we also calculate the quantumness for some detailed mixed-sate ensembles by deriving their analytical formulae.