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AISI type 430 stainless steel is a common current collector in sodium sulfur batteries. The corrosion behavior of stainless steel 430 (SS430) was investigated in this article in a sulfur environment at 350 °C using the gravimetric method. The corrosion mechanism and the characteristics of vulcanization films were studied by diffraction X-ray (XRD) and scanning electron microscopy (SEM), and resistance was tested by a four-probe tester. The results showed that the intensive vulcanization of SS430 took place at a corrosion time above 24 h. The dynamic vulcanization of SS430 first increased to a maximum point of 0.6532 mm × a-1 after 120 h in a 350 °C molten sulfur environment and then decreased. Block resistance reached 0.6058 mΩ after 120 h. The main corrosion product of SS430 was FeS2 within 48 h and its microstructure was porous. The Cr6S7 was observed again after 72 h. A dense Cr2S3 and FeS2 coating formed after 120 h, which protected the SS430 and reduced corrosion.