The construction of a p-n heterojunction is an efficient strategy to resolve the limited light absorption and serious charge-carrier recombination in semiconductors and enhance the photocatalytic activity. However, the promotion effect is greatly limited by poor interfacial charge transfer efficiency as well as reduced redox ability of charge carriers. In this work, we demonstrate that the embedding of metal Pd into the interface between n-type C3N4 and p-type Cu2O can further enhance the interfacial charge transfer and increase the redox ability of charge carriers through the design of the C3N4-Pd-Cu2O stack nanostructure. The embedded Pd nanocubes in the stack structure not only trap the charge carriers from the semiconductors in promoting the electron-hole separation but also act as a Z-scheme "bridge" in keeping the strong reduction/oxidation ability of the electrons/holes for surface reactions. Furthermore, Pd nanocubes also increase the bonding strength between the two semiconductors. Enabled by this unique design, the hydrogen evolution achieved is dramatically higher than that of its counterpart C3N4-Cu2O structure without Pd embedding. The apparent quantum efficiency (AQE) is 0.9% at 420 nm for the designed C3N4-Pd-Cu2O. This work highlights the rational interfacial design of heterojunctions for enhanced photocatalytic performance.

No abstract

This review outlines the recent progress on designing the surface and interface of cocatalysts to create highly efficient photocatalysts for water splitting and CO2reduction.

Due to coarse spatial resolution, the application of Gravity Recovery and Climate Experiment (GRACE) data in local groundwater resource management has been limited. To overcome this issue, a downscaling approach is presented to improve the spatial resolution of GRACE‐derived groundwater storage anomalies using evapotranspiration (ET) data. The statistical downscaling method is only applied in areas where there is a strong relationship between GRACE‐derived groundwater storage (GWS) and ET, and the relationship can be established under different spatial resolutions. In this study, GWS anomalies are downscaled from 110 km to 2 km in the North China Plain, capturing subgrid heterogeneity in groundwater storage changes. The downscaled results are further validated using data from 111 observation wells from 2003 to 2014 in the Beijing Plain. The results show that the in situ groundwater levels agree with the Gravity Recovery and Climate Experiment (GRACE) downscaled results for the Beijing Plain in both interannual and monthly scales, with the correlation coefficient of 0.94 and 0.80, respectively. The correlation coefficients vary from 0.63 to 0.78, in 10 of the 13 Beijing Plain administrative regions. The regional downscaling approach employed in this study may be readily integrated into local water resources planning activities.