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Pentafluorinated phenyl-monohydro[60]fullerenes [C 60 (Ar f ) 5 H] are synthesized in good yields via reaction of the corresponding fluorinated phenyl copper reagent, itself prepared in situ from the fluorinated phenyl Grignard reagent (Ar f MgBr) and copper(I) bromide-dimethyl sulfide complex, with [60]fullerene (C 60 ) in 1,2-dichlorobenzene under a nitrogen atmosphere.

A facile and efficient synthesis of fluorine-containing polyhydrobenzoacridines was accomplished by a three-component coupling of fluorinated aldehyde, α-naphthylamine, and 1,3-cyclohexanedione or dimedone under microwave irradiation and solvent-free conditions without catalyst. All new compounds were obtained in moderate to good yields and characterized by standard spectroscopic methods.

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A facile and efficient synthesis of 14-fluorophenyl-14H-dibenzo[a,j]xanthenes has been developed by one-pot condensation of fluorinated benzaldehydes with β-naphthol in the presence of p-TSA•H 2 O under microwave irradiation and solvent-free conditions. These products are conveniently oxidized to 14-fluorophenyl-14-hydroxydibenzo[a,j]xanthenes by PbO 2 in acetic acid in good yields.