This work aimed to investigate the effectiveness of ultraviolet (UV) radiation on the degradation of the antimicrobial triclocarban (TCC). We investigated the effects of several operational parameters, including solution pH, initial TCC concentration, photocatalyst TiO₂ loading, presence of natural organic matter, and most common anions in surface waters (e.g., bicarbonate, nitrate, and sulfate). The results showed that UV radiation was very effective for TCC photodegradation and that the photolysis followed pseudo-first-order kinetics. The TCC photolysis rate was pH dependent and favored at high pH. A higher TCC photolysis rate was observed by direct photolysis than TiO₂ photocatalysis. The presence of the inorganic ions bicarbonate, nitrate, and sulfate hindered TCC photolysis. Negative effects on TCC photolysis were also observed by the addition of humic acid due to competitive UV absorbance. The main degradation products of TCC were tentatively identified by gas chromatograph with mass spectrometer, and a possible degradation pathway of TCC was also proposed.

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The in-plane dynamic crushing behavior and energy absorption capacity of self-similar hierarchical honeycombs under different impact velocities are numerically studied using ANSYS/LS-DYNA. First, the hierarchical honeycomb models with uniform cell-wall thickness are constructed by replacing every three-edge structure nodes of a regular honeycomb with smaller self-similar hexagons of the same orientation. The respective influences of hierarchical parameters, bulk materials, and impact velocities on the macro-/micro-deformation behaviors, the dynamic strength, and the specific absorbed energy of hierarchical honeycombs are explored in detail. The results show that the crushing strengths and energy-absorbing capacities of honeycombs significantly improve when adding the hierarchy into conventional cellular structures. The variation of hierarchical parameter changes the local dynamic evolution of stress waves, which further results in different macro-/micro-deformation properties. Through the proper choice of hierarchical parameters and bulk materials, the optimal crushing strength and the maximum absorbing energy could be obtained.