Disperse dyeing for polyethylene terephthalate (PET) fiber in different non-aqueous solvent dyeing systems have been extensively studied over the past decades. In the present work, disperse dyeing for PET was investigated in a silicone solvent dyeing system. The influence of accelerant on the fiber swelling, uptake of dye, K/S value of dyed fiber, and dye solubility in the silicone solvent were systematically investigated. Compared with no accelerant, the final uptake of the disperse dye (C. I. Disperse Blue 367) could increase to 81% with 20% accelerant in the silicone solvent dyeing system, and the K/S value of dyed fiber was also higher (3.3 for no accelerant vs. 13.2 for accelerant). The influence of accelerant on the performance of disperse dyeing was also studied. Firstly, the solubility of the disperse dye in the silicone solvent can be decreased by the accelerant. Moreover, the solubility of the disperse dye is inversely proportional to the K/S value and the uptake of the dye. In addition, although the silicone solvent can diffuse to the inner fiber and has a partial swelling in the PET fiber, the swelling of PET can be improved by the accelerant. Furthermore, the swelling of fiber can reach equilibrium when the amount of accelerant was 15% (the weight of fiber). Therefore, this eco-friendly dyeing technology has considerable potential for application to a broad array of chemical fibers.

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