The deposition behaviour of an individual nanofibre on planar and patterned silicon substrates is studied using near-field electrospinning (NFES). A high-speed camera was utilized to investigate the formation and motion process of a liquid jet. Thanks to the shorter distance from the spinneret to the collector, bending instability and splitting of the charged jet in electrospinning were overcome. In NFES, a straight-line jet between the spinneret and the collector can be utilized to direct-write an orderly nanofibre. Perturbation stemming from residual charges on the collector caused the oscillation of the charged jet, and the deposition of the non-woven nanofibre on the planar substrate. With increasing collector speed, the impact of residual charges was weakened by the strong drag force from the collector and a straight-line nanofibre could be obtained. In addition, the nanofibre can be direct-written in a special pattern by controlling the motion track of the collector. Therefore, it can be concluded that a micro-strip pattern was a good guidance for nanofibre deposition, and the nanofibre deposition track followed well along the top surface of the micro-strip pattern. The position-controlled deposition of a single nanofibre provides a new aspect for applications of electrospinning.

Antibacterial air filtration membranes are essential for personal protection during the pandemic of coronavirus disease 2019 (COVID-19). However, high-efficiency filtration with low pressure drop and effective antibiosis is difficult to achieve. To solve this problem, an innovative electrospinning system with low binding energy and high conductivity was built to enhance the jet splitting, and a fluffy nanofibrous membrane containing numerous ultrafine nanofibers and large quantities of antibacterial agents was achieved, which was fabricated by electrospinning polyamide 6 (PA6), poly­(vinyl pyrrolidone) (PVP), chitosan (CS), and curcumin (Cur). The filtration efficiency for 0.3 μm NaCl particles was 99.83%, the pressure drop was 54 Pa, and the quality factor (QF) was up to 0.118 Pa–1. CS and Cur synergistically enhanced the antibacterial performance; the bacteriostatic rates against Escherichia coli and Staphylococcus aureus were 99.5 and 98.9%, respectively. This work will largely promote the application of natural antibacterial agents in the development of high-efficiency, low-resistance air filters for personal protection by manufacturing ultrafine nanofibers with enhanced antibiosis.

No abstract

Increasing the ejection efficiency and uniformity of nanofibers is the key to applications of electrospinning technology. In this work, a novel electrospinning spinneret with a sheath gas passageway is designed. The frictional resistance that stems from the sheath gas provides additional stretching and restriction forces on the jet. The sheath gas also reduces interference and enhances the stability of the charged jet. A bead-on-strain simulation model is built up to determine the constraint effects of the sheath gas. Simulation results show that the sheath gas decreases the motion area and increases the stretching ratio of the liquid jet. The stretching force from the sheath gas decreases the diameter and increases the uniformity of the nanofiber. As the gas pressure increases from 0 kPa to 50 kPa, the critical voltage of the jet ejection decreases from 8.4 kV to 2.5 kV, the diameter of the nanofiber deposition zone decreases from 40 cm to 10 cm, and the diameter of the nanofibers decreases from 557.97 nm to 277.73 nm. The uniformity of nanofibers can be improved significantly using a sheath gas. The sheath gas contributes to the rapid deposition of a uniform nanofibrous membrane and the industrial applications of electrospinning.

Highly efficient air filtration with low pressure drop is the key to air purification. In this work, a self-powered electrospun nanofiber membrane with an electrostatic adsorption effect was prepared to improve the filtration efficiency of micro/nano particles. The composite membrane was comprised of polyvinyl chloride (PVC) nanofibers and polyamide-6 (PA6) nanofibers. The triboelectric effect between the two adjacent nanofiber membranes generated electrostatic charges under the action of air vibration, by which the electrostatic adsorption with the same pressure drop was enhanced. The electrostatic voltage on the self-powered nanofiber membrane was 257.1 mV when the flow velocity was 0.1 m/s. For sodium chloride (NaCl) aerosol particles with a diameter of 0.3 μm, the removal efficiency of the self-powered composite nanofiber membrane was 98.75% and the pressure drop was 67.5 Pa, which showed a higher quality factor than the membrane without electrostatic charges. This work provides an effective way to improve the filtration performance of air filter membranes.