We combine top-down and bottom-up nanolithography to optimize the coupling of small molecular spin ensembles to 1.4 GHz on-chip superconducting resonators. Nanoscopic constrictions, fabricated with a focused ion beam at the central transmission line, locally concentrate the microwave magnetic field. Drops of free-radical molecules have been deposited from solution onto the circuits. For the smallest ones, the molecules were delivered at the relevant circuit areas by means of an atomic force microscope. The number of spins N eff effectively coupled to each device was accurately determined combining Scanning Electron and Atomic Force Microscopies. The collective spin-photon coupling constant has been determined for samples with N eff ranging between 2 × 10 6 and 10 12 spins, and for temperatures down to 44 mK. The results show the well-known collective enhancement of the coupling proportional to the square root of N eff . The average coupling of individual spins is enhanced by more than 4 orders of magnitude (from 4 mHz up to above 180 Hz), when the transmission line width is reduced from 400 μm down to 42 nm, and reaches maximum values near 1 kHz for molecules located on the smallest nanoconstrictions.

Einstein's theory of general relativity and quantum theory form the two major pillars of modern physics. However, certain inertial properties of a particle's intrinsic spin are inconspicuous while the inertial properties of mass are well known. Here, by performing a neutron interferometric experiment, we observe phase shifts arising as a consequence of the spin's coupling with the angular velocity of a rotating magnetic field. The resulting phase shifts linearly depend on the frequency of the rotation of the magnetic field. Our results agree well with the predictions derived from the Pauli -Schrödinger equation.

In neutron interferometric experiments using polarized neutrons coherent spin-rotation control is required. In this letter we present a new method for Larmor spin-rotation around an axis parallel to the outer guide field using topology optimized 3D printed magnets. The use of 3D printed magnets instead of magnetic coils avoids unwanted inductances and offers the advantage of no heat dissipation, which prevents potential loss in interferometric contrast due to temperature gradients in the interferometer. We use topology optimization to arrive at a design of the magnet geometry that is optimized for homogeneity of the magnetic action over the neutron beam profile and adjustability by varying the distance between the 3D printed magnets. We verify the performance in polarimetric and interferometric neutron experiments.

We report an experiment with neutrons in a silicon perfect crystal interferometer, that realizes a quantum Cheshire Cat in a delayed choice setting. In our setup the quantum Cheshire Cat is established by spatially separating the particle and its property (i.e. the neutron and its spin) into the two different paths of the interferometer. The condition for a delayed choice setting is achieved by postponing the choice of path assignment for the quantum Cheshire Cat, i.e. which path is taken by the particle and which by its property, until the point in time when the neutron wave function has already split and entered the interferometer. The results of the experiment suggest not only the fact that the neutrons and its spin are separated and take different paths in the interferometer, but also quantum-mechanical causality is implied, insomuch that the behavior of a quantum system is affected by the choice of the selection at a later point in time.