We review the dynamical mean-field theory of strongly correlated electron systems which is based on a mapping of lattice models onto quantum impurity models subject to a self-consistency condition. This mapping is exact for models of correlated electrons in the limit of large lattice coordination (or infinite spatial dimensions). It extends the standard mean-field construction from classical statistical mechanics to quantum problems. We discuss the physical ideas underlying this theory and its mathematical derivation. Various analytic and numerical techniques that have been developed recently in order to analyze and solve the dynamical mean-field equations are reviewed and compared to each other. The method can be used for the determination of phase diagrams (by comparing the stability of various types of long-1 range order), and the calculation of thermodynamic properties, one-particle Green's functions, and response functions. We review in detail the recent progress in understanding the Hubbard model and the Mott metal-insulator transition within this approach, including some comparison to experiments on three-dimensional transition-metal oxides. We also present an overview of the rapidly developing field of applications of this method to other systems. The present limitations of the approach, and possible extensions of the formalism are finally discussed. Computer programs for the numerical implementation of this method are also provided with this article.
We present a powerful method for calculating the thermodynamic properties of infinitedimensional Hubbard-type models using an exact diagonalization of an Anderson model with a finite number of sites. The resolution obtained for Green's functions is far superior to that of quantum Monte Carlo calculations. We apply the method to the half-filled Hubbard model for a discussion of the metal-insulator transition, and to the two-band Hubbard model where we find direct evidence for the existence of a superconducting instability at low temperatures.
Melting in two spatial dimensions, as realized in thin films or at interfaces, represents one of the most fascinating phase transitions in nature, but it remains poorly understood. Even for the fundamental hard-disk model, the melting mechanism has not been agreed on after fifty years of studies. A recent Monte Carlo algorithm allows us to thermalize systems large enough to access the thermodynamic regime. We show that melting in hard disks proceeds in two steps with a liquid phase, a hexatic phase, and a solid. The hexatic-solid transition is continuous while, surprisingly, the liquid-hexatic transition is of first-order. This melting scenario solves one of the fundamental statistical-physics models, which is at the root of a large body of theoretical, computational and experimental research. Generic two-dimensional particle systems cannot crystallize at finite temperature [1][2][3] because of the importance of fluctuations, yet they may form solids [4]. This paradox has provided the motivation for elucidating the fundamental melting transition in two spatial dimensions. A crystal is characterized by particle positions which fluctuate about the sites of an infinite regular lattice. It has long-range positional order. Bond orientations are also the same throughout the lattice. A crystal thus possesses long-range orientational order. The positional correlations of a two-dimensional solid decay to zero as a power law at large distances. Because of the absence of a scale, one speaks of "quasi-long range" order. In a two-dimensional solid, the lattice distortions preserve long-range orientational order [5], while in a liquid, both the positional and the orientational correlations decay exponentially.Besides the solid and the liquid, a third phase, called "hexatic", has been discussed but never clearly identified in particle systems. The hexatic phase is characterized by exponential positional but quasi-long range orientational correlations. It has long been discussed whether the melting transition follows a one-step first-order scenario between the liquid and the solid (without the hexatic) as in three spatial dimensions Two-dimensional melting was discovered [4] in the simplest particle system, the hard-disk model. Hard disks (of radius σ) are structureless and all configurations of nonoverlapping disks have zero potential energy. Two isolated disks only feel the hard-core repulsion, but the other disks mediate an entropic "depletion" interaction (see, e.g., [19]). Phase transitions result from an "order from disorder" phenomenon: At high density, ordered configurations can allow for larger local fluctuations, thus higher entropy, than the disordered liquid. For hard disks, no difference exists between the liquid and the gas. At fixed density η, the phase diagram is independent of temperature T = 1/k B β, and the pressure is proportional to T , as discovered by D. Bernoulli in 1738. Even for this basic model, the nature of the melting transition has not been agreed on.The hard-disk model has been simulated with the...
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