Nano‐scale zero‐valent iron (nZVI) attached to Fe3O4 nanoparticles (Fe0@Fe3O4), which has better dispersibility and a larger specific surface area than the nanoparticles alone, were prepared and applied to the reductive dechlorination of carbon tetrachloride (CT). CT removal efficiencies by Fe0@Fe3O4 composites with different ratios of the two components were compared. Under optimum conditions, when the Fe0/Fe3O4 ratio was 1:2, almost no CT was detected after 50 min and it took only about 30 min to reach a removal efficiency of 90%, compared with 120 min for an Fe0/Fe3O4 ratio of 1:4. An increase in the amount of nZVI in the catalyst effectively improved the removal of CT and accelerated the reaction rate. Chloroform was the main product. Compared with Fe3O4 alone, a significant increase in the solution concentrations of ferrous and ferric ions occurred in the Fe0@Fe3O4 system: both Fe2+ and Fe3+ reached their maximum concentrations at 60 min and then tended to decline over the next 60 min. The increase in Fe2+ concentration was attributed to the reaction between nZVI and CT, which produces ferrous ions when electrons transfer from Fe0 to organic chlorides. Synergistic effects between the composite constituents promoted the relative rates of mass transfer to reactive sites and Fe2+ generated in solution facilitated the reduction of chlorinated organic pollutants by magnetite. Thus, Fe0@Fe3O4 nanoparticles effectively achieved reductive dechlorination of CT and provide an improved nZVI catalyst for the remediation of chlorinated organic compounds.

Manganese (Mn) is an essential element for human body. However, elevated concentration of manganese causes severe problem and disease. Acid mine drainage (AMD), wastewater generated due to open-pit mining, commonly contains Mn with exceeded concentration. This study is to investigate the improvement of ball-milling modified Indonesian natural bentonite (INB) for manganese (Mn) removal from AMD and to increase the pH through batch and column sorption test as a passive treatment system approach. The batch sorption test result showed the maximum Mn adsorbed (Q m ) on INB from the Langmuir model increased from 4.69 to 17.12 mg/g after milling. The column sorption test result also showed the amount of Mn adsorbed on INB until breakthrough time (q u ) and until saturation time (q) increased after milling. The q u increased from 1.27 to 10.06 mg/g, and the q increased from 4.55 to 12.91 mg/g. The mass transfer zone (MTZ) became significantly shorter after milling from 0.22 to 0.07 cm. The Thomas model exhibited the equilibrium uptake of Mn (q 0 ) increased after milling from 3.91 to 13.72 mg/g. In equilibrium condition, both unmilled and milled INB showed the pH increased from ≈3 to 8.

Claystone middle Miocene age were found in Wonosegoro sub-district, Boyolali region, Central Java, Indonesia. The purpose of the paper is to examine and discuss the geology and typical behavor of this claystone and its micro-level mechanism. The hydraulic conductivity was assessed using consilidated apparatuses; 150 mm diameter column mound using aggregated sample and 60 mm oedometer mould using slurry sample as a reference. Claystone materials used were treated under various conditions. In long term test under constand vertical stress and hydraulic gradient, the hydraulic conductvity decreases with time although the volume of void volume of the sample increased by swelling. Water contens of the individul aggregated increased by swelling, by which strength of particles decreases with and aggregate breakdown was enchanced. As a result, large void created by large particles could be redused in its size, leading the reduction of hydraulic conductuvity. The hydralic conductivities (K values) obtained from the aggregated sample varied in a broad range compared with those from slurry sample. In the test using the higher percentage of gravel-sized aggregate (up until couarse gravel-sized; retained in 26.5 mm sieve), K values changed from 10-5 to 10-7 m/s under vertical stresses from 5 up to 245 kPa. The test was repeated using smaller percentage of gravel-sized aggregate (up until fine gravel-sized, retained in 4.75 mm sieve) and the observed K values changed from 10-5 to 10-10 m/s. While the K values obtained in the specimen made from surry under same vertical stresses was 10-9 to 10-11 m/s. All of the extruded aggregate samples had higher water content than the initial ones, which suggest the alteration mechanism of soled consolidation phase to more deformable plastic phase, whice enables thesample to decrease the void size. These results conclude that using coarse gravel-sized aggregated, which is a reasonable scenario of a practically feasible aggregate size in a field, may noy produce the aimed hydraulic conductivity by the regulated standard. Therefore, breakdown of the aggrgate size and enchament of swelling are crucial factors for the application of the clay stones as a barrier material.

The influences of mechanical milling on Indonesian Natural Bentonite (INB) characteristics and manganese (Mn) removal from acid mine drainage (AMD) were investigated. The INB characteristics were observed by scanning electron microscope (SEM), X-ray diffraction (XRD), nitrogen adsorption-desorption for specific surface area (SSA) and microporosity measurement, cation exchange capacity (CEC) and particle size distribution (PSD) analyzer. Four minutes milling with frequency 20 Hz on INB caused morphological change which showed more crumbled and destructed particle, lost the (001) peak but still retained the (100) peak that indicated delamination of montmorillonite mineral without breaking the tetrahedral-octahedral-tetrahedral (T-O-T) structure, rose the CEC from 28.49 meq/100g to 35.51 meq/100g, increase in the SSA from 60.63 m2/g to 104.88 m2/g, significant increase in microporosity which described in the t plots and decrease in the mean particle size distribution peak from 49.28 μm to 38.84 μm. The effect of contact time and effect of adsorbent dosage on Mn sorption was studied. Both unmilled and milled samples reached equilibrium at 24 hours and the pH rose from 4 to 7 in first 30 minutes. The Mn removal percentage increased significantly after milling. Using Langmuir isotherm, the maximum adsorbed metals (qmax) also increased from 0.570 to 4.219 mg/g.