To a solution of (Ia) in CH2Cl2 was added phenoxathiinium hexachloroantimonate, the resulting oxidation product, the complex (IIa), was shown to be an iron(III) porphyrin π‐cation radical rather than an iron(IV) compound.
IIIS, bond distances; Table IVS, bond angles; listings of magnetic susceptibility data for [Cu(TMP')][SbCl6]-C6H5F and [VO-(TPP')] [SbCl6] (9 pages); listings (X10) of the observed and calculated structure amplitudes of [Cu(TPP')][SbCl6] (13 pages). Ordering information is given on any current masthead page.
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