Using friction force microscopy, we compared the nanoscale frictional characteristics of atomically thin sheets of graphene, molybdenum disulfide (MoS2), niobium diselenide, and hexagonal boron nitride exfoliated onto a weakly adherent substrate (silicon oxide) to those of their bulk counterparts. Measurements down to single atomic sheets revealed that friction monotonically increased as the number of layers decreased for all four materials. Suspended graphene membranes showed the same trend, but binding the graphene strongly to a mica surface suppressed the trend. Tip-sample adhesion forces were indistinguishable for all thicknesses and substrate arrangements. Both graphene and MoS2 exhibited atomic lattice stick-slip friction, with the thinnest sheets possessing a sliding-length-dependent increase in static friction. These observations, coupled with finite element modeling, suggest that the trend arises from the thinner sheets' increased susceptibility to out-of-plane elastic deformation. The generality of the results indicates that this may be a universal characteristic of nanoscale friction for atomically thin materials weakly bound to substrates.
2The enormous stiffness and low density of graphene make it an ideal material for nanoelectromechanical (NEMS) applications. We demonstrate fabrication and electrical readout of monolayer graphene resonators, and test their response to changes in mass and temperature. The devices show resonances in the MHz range. The strong dependence of the resonant frequency on applied gate voltage can be fit to a membrane model, which yields the mass density and built-in strain. Upon removal and addition of mass, we observe changes in both the density and the strain, indicating that adsorbates impart tension to the graphene. Upon cooling, the frequency increases; the shift rate can be used to measure the unusual negative thermal expansion coefficient of graphene. The quality factor increases with decreasing temperature, reaching ~10 4 at 5 K. By establishing many of the basic attributes of monolayer graphene resonators, these studies lay the groundwork for applications, including high-sensitivity mass detectors.Since its discovery in 2004 1 , graphene has attracted attention because of its unusual two dimensional (2D) structure and potential for applications [2][3][4] . Due to its exceptional mechanical properties 5 and low mass density, graphene is an ideal material for use in nanoelectromechanical systems (NEMS), which are of great interest both for fundamental studies of mechanics at the nanoscale and for a variety of applications, including force 6 , position 7 and mass 8 sensing. Recent studies using optical and scanned probe detection have shown that micron-size graphene flakes can act as MHz-range NEMS resonators 9,10 . Electrical readout of these devices is important for integration and attractive for many applications. In addition, characterization of the basic attributes of these devices, including their response to applied voltage, added mass, and changes 3 in temperature, allows detailed modeling of their behavior, which is crucial for rational device design.Samples are fabricated by first locating monolayer graphene flakes on Si/SiO 2 substrates, then patterning metal electrodes and etching away the SiO 2 to yield suspended graphene. The ability to choose monolayers in advance provides control of device properties and facilitates electrical readout. The fabrication method also provides control over the lateral dimensions; devices can be either micron-wide sheets (Fig. 1a) or lithographically defined nanoribbons (Fig.1b). Because the etchant diffuses freely under the sheets, the SiO 2 is removed at the same rate everywhere under the graphene, so that the distance between the substrate and the suspended sheet is constant (~100 nm) across each device. For the same reason, the portion of each electrode that contacts the graphene is also suspended 11,12 , as depicted in Fig. 1c.Following previous work 13-15 , we implemented an all-electrical high-frequency mixing approach ( Fig. 1d) and 5). In addition to being of fundamental interest as a coupled nanoscale-microscale system, these resonances demonstrate that grap...
Table of Contents:Mazzeo et al. describe methods of patterning metallized paper to create touch pads of arrayed buttons that are sensitive to contact with both bare and gloved fingers. The paper-based keypad shown detects the change in capacitance associated with the touch of a finger to one of its buttons. Mounted to an alarmed cardboard box, the keypad requires the appropriate sequence of touches to disarm the system. Image for Table of Contents:Submitted to 2 This paper describes low-cost, thin, and pliable touch pads constructed from a commercially available, metallized paper commonly used as packaging material for beverages and book covers. The individual keys in the touch pads detect changes in capacitance or contact with fingers by using the effective capacitance of the human body and the electrical impedance across the tip of a finger. To create the individual keys, a laser cutter ablates lines through the film of evaporated aluminum on the metallized paper to pattern distinct, conductive regions. This work includes the experimental characterization of two types of capacitive buttons and illustrates their use with applications in a keypad with 10 individually addressable keys, a keypad that conforms to a cube, and a keypad on an alarmed cardboard box. With their easily arrayed keys, environmentally benign material, and low cost, the touch pads have the potential to contribute to future developments in disposable, flexible electronics, active, "smart" packaging, user interfaces for biomedical instrumentation, biomedical devices for the developing world, applications for monitoring animal and plant health, food and water quality, and disposable games (e.g., providers of content for consumer products).There is no simple method of integrating buttons with structures on single-use or throwaway devices. Current commercial buttons are not thin enough, inexpensive enough, or easy enough to array seamlessly with paper-based products for disposable applications. The touch pads in this work are thin (~60 µm in some cases), simple to array, fabricated by etching patterns into metallized paper, low-cost (< $0.25 m -2 for the thin grade of metallized paper we use in this work), and lightweight (100s of g m -2 ). The individual keys measure changes in capacitance when touched by a user, and the buttons require no physical displacement of conductive elements. Even though the individual keys on the touch pads detect changes in capacitance, the paper-based keypads are still functional when touched by fingers in nitrile gloves. Submitted to 3Developments in paper-based electronics include ring oscillators with organic electronics [1] , transistors [2][3][4] , methods for patterning conductive traces [5][6][7] , speakers [8] , super capacitors [9] , batteries [10] , MEMS [11] , and solar cells [12] . Each of these developments focuses on a single technological advance that would enable new types of consumer products. Many types of new consumer products will require some form of user interface or input. In order to gather ke...
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