New functional materials can in principle be created using colloids that self-assemble into a desired structure by means of a programmable recognition and binding scheme. This idea has been explored by attaching 'programmed' DNA strands to nanometre- and micrometre- sized particles and then using DNA hybridization to direct the placement of the particles in the final assembly. Here we demonstrate an alternative recognition mechanism for directing the assembly of composite structures, based on particles with complementary shapes. Our system, which uses Fischer's lock-and-key principle, employs colloidal spheres as keys and monodisperse colloidal particles with a spherical cavity as locks that bind spontaneously and reversibly via the depletion interaction. The lock-and-key binding is specific because it is controlled by how closely the size of a spherical colloidal key particle matches the radius of the spherical cavity of the lock particle. The strength of the binding can be further tuned by adjusting the solution composition or temperature. The composite assemblies have the unique feature of having flexible bonds, allowing us to produce flexible dimeric, trimeric and tetrameric colloidal molecules as well as more complex colloidal polymers. We expect that this lock-and-key recognition mechanism will find wider use as a means of programming and directing colloidal self-assembly.

Topological mechanical metamaterials are artificial structures whose unusual properties are protected very much like their electronic and optical counterparts. Here, we present an experimental and theoretical study of an active metamaterial-composed of coupled gyroscopes on a lattice-that breaks time-reversal symmetry. The vibrational spectrum displays a sonic gap populated by topologically protected edge modes that propagate in only one direction and are unaffected by disorder. We present a mathematical model that explains how the edge mode chirality can be switched via controlled distortions of the underlying lattice. This effect allows the direction of the edge current to be determined on demand. We demonstrate this functionality in experiment and envision applications of these edge modes to the design of oneway acoustic waveguides.topological mechanics | gyroscopic metamaterial | metamaterial A vast range of mechanical structures, including bridges, covalent glasses, and conventional metamaterials, can be ultimately modeled as networks of masses connected by springs (1-6). Recent studies have revealed that despite its apparent simplicity, this minimal setup is sufficient to construct topologically protected mechanical states (7-11) that mimic the properties of their quantum analogs (12). This follows from the fact that, irrespective of its classic or quantum nature, a periodic material with a gapped spectrum of excitations can display topological behavior as a result of the nontrivial topology of its band structure (13-21).All such mechanical systems, however, are invariant under time reversal because their dynamics are governed by Newton's second law, which, unlike the Schrödinger equation, is second order in time. If time-reversal symmetry is broken, as in recently suggested acoustic structures containing circulating fluids (16), theoretical work (13) has suggested that phononic chiral topological edge states that act as unidirectional waveguides resistant to scattering off impurities could be supported. In this paper, we show that by creating a coupled system of gyroscopes, a "gyroscopic metamaterial," we can produce an effective material with intrinsic time-reversal symmetry breaking. As a result, our gyroscopic metamaterials support topological mechanical modes analogous to quantum Hall systems, which have robust chiral edge states (22)(23)(24). We demonstrate these effects by building a real system of gyroscopes coupled in a honeycomb lattice. Our experiments show long-lived, unidirectional transport along the edge, even in the presence of significant defects. Moreover, our theoretical analysis indicates that direction of edge propagation is controlled both by the gyroscope spin and the geometry of the underlying lattice. As a result, deforming the lattice of gyroscopes allows one to control the edge mode direction, offering unique opportunities for engineering novel materials.Much of the counterintuitive behavior of rapidly spinning objects originates from their large angular momentum, which endows th...

Hexagons can easily tile a flat surface, but not a curved one. Introducing heptagons and pentagons (defects with topological charge) makes it easier to tile curved surfaces; for example, soccer balls based on the geodesic domes of Buckminster Fuller have exactly 12 pentagons (positive charges). Interacting particles that invariably form hexagonal crystals on a plane exhibit fascinating scarred defect patterns on a sphere. Here we show that, for more general curved surfaces, curvature may be relaxed by pleats: uncharged lines of dislocations (topological dipoles) that vanish on the surface and play the same role as fabric pleats. We experimentally investigate crystal order on surfaces with spatially varying positive and negative curvature. On cylindrical capillary bridges, stretched to produce negative curvature, we observe a sequence of transitions-consistent with our energetic calculations-from no defects to isolated dislocations, which subsequently proliferate and organize into pleats; finally, scars and isolated heptagons (previously unseen) appear. This fine control of crystal order with curvature will enable explorations of general theories of defects in curved spaces. From a practical viewpoint, it may be possible to engineer structures with curvature (such as waisted nanotubes and vaulted architecture) and to develop novel methods for soft lithography and directed self-assembly.

Knots and links have been conjectured to play a fundamental role in a wide range of physical fields, including plasmas and fluids, both quantum and classical. In fluids, the fundamental knottedness-carrying excitations occur in the form of linked and knotted vortex loops, which have been conjectured to exist for over a century. Although they have been the subject of considerable theoretical study, their creation in the laboratory has remained an outstanding experimental goal. Here we report the creation of isolated trefoil vortex knots and pairs of linked vortex rings in water using a new method of accelerating specially shaped hydrofoils. Using a high-speed scanning tomography apparatus, we measure their three-dimensional topological and geometrical evolution in detail. In both cases we observe that the linked vortices stretch themselves and then deform-as dictated by their geometrically determined energy-towards a series of local vortex reconnections. This work establishes the existence and dynamics of knotted vortices in real fluids.