RESUMEN El área suroeste de la costa ecuatoriana es una región tradicionalmente petrolera, sin embargo aún no se ha definido cuál es el sistema petrolero reinante en la región. Entre las principales rocas propuestas como generadoras de los crudos del litoral, se encuentran las formaciones Seca y Socorro del Eoceno así como Dos Bocas y Subibaja del Mioceno. Con la finalidad de aportar nuevos elementos al conocimiento de la zona, fueron estudiados tanto crudos como rocas provenientes de campos onshore y offshore, usando técnicas geoquímicas que incluyen cromatografía de gases e isótopos de carbono. Parámetros como el Índice Preferencial de Carbonos (IPC), Pri/ n-C 17 , Fit/n-C 18 y las distribuciones isotópicas, indican que los crudos de los campos onshore están genéticamente diferenciados de los crudos offshore, y se asocian con una roca madre clástica con aporte de materia orgánica mixta, depositada en ambiente subóxico, consistente con la parte distal de un complejo estuarino. Por otro lado, las rocas analizadas son inmaduras térmicamente y con muy bajo potencial generador, por lo que no pueden ser correlacionadas con los crudos analizados, tal y como se venía haciendo tradicionalmente. Palabras clave: geoquímica; roca madre; madurez térmica; Golfo de Guayaquil; Ecuador. Geochemical correlation between oils and rocks of the petroleum system of the Santa Elena peninsula and the gulf of Guayaquil ABSTRACT The southeastern of the Ecuadorian coast is a traditionally oil producing region, but the petroleum system has not been defined yet. The proposed main source rocks are Seca and Socorro formations (Eocene) and Dos Bocas and Subibaja formations (Miocene). In order to contribute new elements to the knowledge of the area, both crude and rock from onshore and offshore fields were studied, using geochemical techniques that include gas chromatography and carbon isotopes. Parameters such as the Carbon Preference Index (IPC), Pri/n-C 17 and Phy/n-C 18 ratios and the isotopic distributions, indicate that onshore oils are genetically differentiated from offshore oils and are associated with a detritic source rock with mixed organic matter, deposited in a suboxic environment, consistent with the distal area of an estuarine complex. On the other hand, the rocks analyzed are thermally immature and with very low generating potential, so that they cannot be correlated with the crude analyzed, as was traditionally done.
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