Purpose This paper aims to explore the effects of mineral diesel fuel carbon soot (MCS) and biodiesel carbon soot (BCS) on the lubrication of polyalphaolefin (PAO) and diesel fuels. Design/methodology/approach Two styles of carbon soot were prepared from the natural combustion of mineral diesel fuel oil (MDO) and biodiesel oil (BDO). Tribological tests were conducted on a high-frequency reciprocating rig. Friction surfaces were characterized using three-dimensional laser scanning confocal microscopy and Raman spectroscopy. Findings The addition of MCS and BCS to PAO could reduce friction in most cases. MCS had a negligible effect on the wear for contents not exceeding 1.0 per cent. By contrast, BCS exhibited a considerable negative influence on the wear resistance even at low contents. For diesel fuels, MCS reduced both friction and wear, whereas BCS substantially deteriorated the lubrication of BDO. MCS formed a Fe3O4/C composite lubricating film on the friction surface. BCS also entered the contact region, but it did not form an effective Fe3O4/C composite lubricating film. Originality/value This work compared MDO and BDO from a different perspective, i.e. the effects of their combustion carbon soot on the lubrication of lubricating oil and fuel oil. The significant negative effect of BCS on the lubrication of lubricating oil and BDO is a problem that could occur in the industrial application of BDO.
Purpose The purpose of this paper is to explore the tribological properties of high-density polyethylene (HDPE) modified by carbon soot from the combustion of No. 0 diesel. Design/methodology/approach Carbon soot is characterized using X-ray diffraction, transmission electron microscopy and scanning electronic microscopy. The tribological properties of HDPE samples with carbon soot are investigated on a materials surface tester with a ball-on-disk friction pair. Findings The collected carbon soot mainly comprises amorphous carbon nanoparticles of 50-100 nm in diameter. The main wear behaviours of pure HDPE include abrasive wear and plastic deformation. After adding carbon soot nanoparticles to HDPE, HDPE wear decreases. The appropriate carbon soot content is 8 per cent in HDPE under the selected testing conditions. Compared with other HDPE samples, HDPE with 8 per cent carbon soot has higher melting temperature, lower abrasive wear and better wear resistance. The lubrication of HDPE with carbon soot is due to the formation of a transferring film composed of HDPE, amorphous carbon and graphite carbon. Originality/value The paper reveals the HDPE modification and lubrication mechanisms by using carbon soot from the combustion of diesel. Related research can perhaps provide a potential approach for the treatment of carbon soot exhaust emission.
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