Light-scattering studies of the liquid-glass transition of Cao, 4Ko.e(NOs)&. 4 have been carried out from 305 to 23'C. Composite spectra covering over four decades in frequency were obtained by combining data obtained with a Sandercock tandem Fabry-Perot interferometer and Raman spectra. Two-step relaxation processes were observed in the supercooled liquid near the glass transition. The e relaxation exhibits a temperature-independent stretching for T~T, with T, 105'C, which is about 45 'C above the glass transition temperature. The P-relaxation frequency scale indicates critical slowing down when the temperature approaches T, from either above or below. Scaling analyses for both o and P relaxations provide good agreement with the predictions of mode-coupling theory.PACS number(s): 64.70.Pf, 78.35.+c, 46.30.Jv

No abstract

No abstract

Brillouin scattering from the six pure transverse acoustic modes of KqSe04 from 80 to 300 K was investigated. The temperature dependence of the hypersonic shear elastic constants C4&, C&5 and C66 and the corresponding damping constants were obtained. C44 and C66 show anomalies near T; and C55 near T, closely resembling the results of ultrasonic experiments. The C44 anomaly was analyzed in terms of bilinear coupling to the lowest temperature-dependent B3g optical mode, which was observed in Raman scattering. The C» anomaly near T, was compared with the plane-waveapproximation result for the coupling of the strain to the phason. For the three pairs of transverse acoustic modes there was no asymmetry observed in the incommensurate and commensurate phases under interchange of the propagation and polarization directions.