a b s t r a c tThe Wonoka-Shuram Anomaly represents the largest negative carbon isotope excursion recognized in the geologic record and is associated with the emergence and diversification of metazoan life ca. 580 million years ago (Ma). The origin of the anomaly is highly debated, with interpretations ranging from primary to diagenetic, each having unique and potentially transformative implications for early life. Here, we apply carbonate clumped isotope thermometry to three sections expressing the anomaly in order to constrain mineral formation temperatures and thus directly calculate water oxygen isotope compositions (␦ 18 O w ) with which carbonate minerals equilibrated. With ␦ 18 O w known, it is possible to address previous hypotheses for the origin of the anomaly. In each section, precipitation temperatures correlate positively with reconstructed ␦ 18 O w . Previous hypotheses, based on the covariance of ␦ 18 O carb vs. ␦ 13 C carb (uncorrected for temperature effects), suggested a meteoric diagenetic origin for the anomaly. However, reconstructed ␦ 18 O w values do not covary with carbon isotope compositions (␦ 13 C carb ) within anomaly facies. Rather, the oxygen isotope and temperature data are consistent with carbonate recrystallization and equilibration under increasingly rock-buffered conditions. Based on simple modeling and comparison to modern formation fluids, recrystallization may have occurred in an environment far removed from the initial depositional or early diagenetic regime. In addition, although clumped isotope temperatures vary significantly and reach elevated values consistent with burial diagenesis, it is unclear to what degree, if at all, carbon isotope values were reset during recrystallization. Ultimately, these new data indicate that Wonoka-Shuram-aged carbonates experienced equilibration with fluids under increasingly closedsystem conditions. The clumped isotope data do not provide a means to distinguish previous hypotheses outright, but provide additional context for the evaluation of geochemical signatures within these ancient carbonate rocks.

Kaolinite is a common mineral found in most Chinese sandstone-hosted uranium deposits. It occurs particularly in coal-bearing clastic rocks in northwest China, such as the uranium deposits in the Yili Basin, which is well known for hosting several largescale roll-front uranium deposits. Previous studies have provided limited information on the origin of kaolinization and its role in the uranium mineralization. This study uses gas hydrocarbon, fluid inclusions, O and H isotope analysis, and scanning electron microscopy observations to investigate the formation of kaolinite in ore-hosting rocks from the Mengqiguer uranium deposit in the southern margin of the Yili Basin and to determine its role in the uranium mineralization. Results suggest that kaolinization is intense in the coal-and ore-bearing clastic rocks and that it is related to leaching of feldspar by acidic fluids. Vermicular kaolinite was formed by hydrocarbon-bearing fluid generated from coal and carbonaceous mudstone during a shallow-burial diagenetic stage at low homogenization temperatures ranging from 69 to 78 ∘ C and at relatively high salinities of 7.6−11.0 wt% NaCl eq . Consequently, silicate minerals (such as feldspar) were leached and created secondary pores that hosted the subsequently formed uranium minerals. In contrast, micritic kaolinite was formed by infiltration of meteoric fluid enriched in U and O 2 at low homogenization temperatures of 51−63 ∘ C and low salinities of 1.2−3.7 wt% NaCl eq . U 6+ was sorbed by the micritic kaolinite through cation exchange, forming a U-bearing kaolinite complex; it was also reduced by pyrite and carbon detrital, thereby precipitating at the acidic oxidation front. The results of this study confirm that intense kaolinization is closely related to uranium mineralization in coal-bearing clastic rocks.

This comprehensive analysis investigated the causes of formation densification in the Shan-1 Member tight reservoir in the southwestern Ordos Basin. The study aimed to mitigate exploration and development risks by examining petrological characteristics, reservoir performance, pore characteristics, and pore evolution. Various techniques were employed, including thin-section casting, scanning electron microscopy, and analysis of porosity and permeability. By establishing the relationship between visualized reservoir porosity and thin slice porosity, along with employing mechanical compaction correction methods and the principle of “back stripping by inversion,” the recovery of paleophysical properties in tight sandstone reservoirs was conducted. Additionally, the research integrated diagenetic evolution sequences and the recovery of paleophysical properties to analyze the origins of reservoir densification and pore evolution in the Shan-1 Member. The results suggest that compaction is the primary factor contributing to reservoir densification, with burial depth playing a crucial role in determining the intensity of compaction. Cementation, particularly associated with illite, emerged as a significant influence on reservoir densification, while low dissolution also contributed to the densification process. The densification of the Shan-1 reservoir in the study area was estimated to have occurred during the Early Jurassic, approximately 195 Ma. These research findings not only enhance the understanding of the Shan-1 reservoir but also provide valuable insights for predicting tight reservoirs and improving the efficiency of oil and gas production.

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