Microperoxidase-11 has for the first time been successfully immobilized into a mesoporous metal-organic framework (MOF) consisting of nanoscopic cages and it demonstrates superior enzymatic catalysis performances compared to its mesoporous silica counterpart.

Gas separation using molecular sieves (MSs) is a environmentally benign, energy-conserving alternative to traditional separation processes, such as distillation and absorption. [1] When using zeolite MSs, [2][3][4] an accurate one-on-one match between the mesh size and the separation need is essential. However, when the size disparity of the two gases to be separated is small, a MS with the optimum mesh size is not always readily available. A mismatch inevitably leads to an inefficient separation. Recently, titanosilicate was shown to possess superior flexibility over that of traditional zeolites; a few MSs with discrete mesh sizes were made based on the degree of dehydration of this material at various temperatures.[5] Nevertheless, a MS with more than one mesh size has never been made in the past. Herein, we report the design, synthesis, and application of a novel mesh-adjustable molecular sieve (MAMS-1) that possesses an infinite number of mesh sizes. MAMS-1 is based on a metal-organic framework (MOF), compounds known for their dynamic porous properties.[6] However, the concept of a MAMS has never appeared in the literature prior to the present work. MAMS-1 represents a MOF-based MS whose mesh can be adjusted continuously. The mesh range of MAMS-1 falls between 2.9 and 5.0 , which covers the size range of almost all commercially important gas separations. When the temperature is precisely controlled, any mesh size within this range can be accurately attained. Gas separations such as those of N 2 /O 2 and N 2 /CH 4 , which are normally difficult to achieve, are readily attainable by using MAMS-1. In principle, by precise temperature control, any two gases with a size difference can be separated by a MAMS.MOFs have attracted a great deal of attention because of their unique structures [6a, 7] and potential applications in catalysis, [8] separation, [9] and gas storage. [10] In particular, flexible MOFs [6] have caught enormous attention lately. Numerous studies have indicated that the key to constructing a flexible MOF lies in the utilization of weak interactions, such as hydrogen bonding, p-p stacking, and hydrophobic interaction, in addition to strong covalent and coordinative bonding.[6] Flexible MOFs based on hydrogen bonding have been widely studied, [6b,c] but those originating from p-p stacking and hydrophobic interaction [11] have rarely been explored.To make a MAMS, two factors must be taken into account: the material must have permanent porosity to hold gas molecules, and the pores must be flexible. The former usually requires strong bonds, while the latter implies weak interactions in the framework. These two seemingly irreconcilable prerequisites for a MAMS can be met simultaneously by using a graphitic structure, in which atoms in each layer are connected covalently but the layers are held together by weak interactions. One approach to such a graphitic MOF is to apply an amphiphilic ligand that consists of hydrophobic and hydrophilic ends, similar to a surfactant, [12] but with the hydrophilic ...

Open and close: Inspired by close‐packing of spheres, to strengthen the framework–H2 interaction in MOFs (metal‐organic frameworks), a strategy is devised to increase the number of nearest neighboring open metal sites of each H2‐hosting cage, and to align the open metal sites toward the H2 molecules. Two MOF polymorphs were made, one exhibiting a record high hydrogen uptake of 3.0 wt % at 1 bar and 77 K.

A mesoporous metal-organic framework possessing permanent porosity has been synthesized and characterized for the first time.