Series battery equalisation can improve battery charge and discharge reliability and extend battery life. Inductor-based battery equalisation schemes have the advantages of simple topologies and control strategies. According to the energy transfer pathway, inductor-based battery equalisation schemes can be divided into cell-to-cell and cell-to-pack equalisation schemes. The control strategies of the cell-to-cell schemes are simple; the inductor can only transfer energy between the neighbouring cells, so the equalisation speed is low. The cell-to-pack schemes are able to accomplish energy transfer between the cells and pack by charging and discharging the inductors. The equalisation speed is high, but the control strategies may be complex. In this paper, different equalisation topologies are reviewed, then a unified control strategy which is applicable to all of the inductor-based equalisation topologies is proposed. The equalisation speeds and efficiencies of these different schemes, including the newly-proposed unified control strategy, are analysed and compared. Based on the theoretical analysis, simulations, and experimental verifications, it is concluded that this unified control strategy can perform the battery equalisation process quickly and efficiently.

The perovskite layer contains a large number of charged defects that seriously impair the efficiency and stability of perovskite solar cells (PSCs), thus it is essential to develop an effective passivation strategy to heal them. Based on theoretical calculations, it is found that enhancing the electrostatic potential of passivators can improve passivation effect and adsorption energy between charged defects and passivators. Herein, an electrostatic potential modulation (EPM) strategy is developed to design passivators for highly efficient and stable PSCs. With the EPM strategy, 1‐phenylethylbiguanide (PEBG) and 1‐phenylbiguanide (PBG) are designed. It is found that the charge distribution and electrostatic potential of phenyl‐ and phenylethyl‐ substituent on the biguanide are significantly enhanced. The N atom directly bonding to the phenyl group shows larger positive charge than that bonding to the phenylethyl group. The modulated electrostatic potential makes PBG bind stronger with the defects on perovskite surface. Based on the effective passivation of EPM, a champion efficiency of 24.67% is realized and the device retain 91.5% of its initial PCE after ≈1300 h. The promising EPM strategy, which provides a principle of passivator design and allows passivation to be controllable, may advance further optimization and application of perovskite solar cells toward commercialization.

No abstract

No abstract

No abstract