In this work, a new ultra-high strength Al-Cu-Li alloy was investigated. The ultimate strength, yield strength and elongation of the newly designed alloy by artificial aging are 647.2MPa, 609.4MPa and 7.3% respectively. Among the main strengthening phases of T1, θ′ and S′ in the experimental alloys, T1is the dominant one. The combined addition of Mg and Ag promoted the precipitation of T1and increased the strength of the new alloy greatly. Zn had a similar effect as Ag during the aging strengthening progress, when added with Mg. Among the three micro-alloying elements, Mg, Ag and Zn, Mg had the strongest influence on age strengthening. Compared with the combined additions of (Mg +Ag) and (Mg + Zn), (Ag + Zn) had the weakest influence on aging strengthening. Pre-deformation before aging promoted the precipitation of T1 phase which weakened the influence of micro-alloying elements (Mg, Ag and Zn) on strengthening the alloys and minished the strength difference between alloy containing (Mg + Ag + Zn) and alloys containing two of them.
Microstructure evolution and mechanical properties of a 1469 alloy and a Sc-free1469 type alloy were examined. SEM observation indicates that AlCuSc ternary phases (W) are formed after homogenization annealing, and cannot be dissolved during the following heat treatments. These coarse particles consume abundant Cu atoms from the Al matrix that are available for solutioning, which results in the decrease of precipitation of the T1 phase during aging treatment. The W phase has negative effects on the examined alloy’s mechanical properties. The tensile strength of Sc-added alloy is 40MPa lower than that of the Sc-free alloy. The formation of the W phase has a close relationship with Cu/Sc ratio, which shows the importance of controlling the concentration of Cu and addition of Sc. Formation of W phase suppress the effect of precipitation hardening of the T1 phase in high strength Al-Cu-Li alloys
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