A new synthetic approach for the formation of ultrathin polymer films with customizable properties was developed. In this approach, the kinematic nature of proton collisions with simple organic molecules condensed on a substrate is exploited to break C-H bonds preferentially. The subsequent recombination of carbon radicals gives a cross-linked polymer thin film, and the selectivity of C-H cleavage preserves the chemical functionalities of the precursor molecules. The nature and validity of the method are exemplified with theoretical results from ab initio molecular dynamics calculations and experimental evidence from a variety of characterization techniques. Its applicability is demonstrated by the synthesis of ultrathin polymer films with precursor molecules such as dotriacontane, docosanoic acid, poly(acrylic acid) oligomer, and polyisoprene. The approach is fundamentally different from conventional chemical synthesis as it involves an unusual mix of physical and chemical processes including charge exchange, projectile penetration, kinematics, collision-induced dissociation, inelastic energy transfer, chain transfer, and chain cross-linking.

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Broadband terahertz (THz) absorbers are highly desired in detection, modulation, receiving, and imaging devices. We report the design and successful implementation of a novel broadband THz metasurface with a near-perfect absorption. Different from the traditional metal/dielectric/metal three-layer structures, the as-designed THz absorber has one more metal layer and a dielectric spacer on top, both of which are 200 nm thick. Although the total thickness increased by ∼7%, the near-perfect THz absorption band significantly broadened by 4×, achieving a broadband absorption of 270 GHz. Broadband, polarization-insensitive, and near-perfect THz absorptions were also observed over wide incident angles in these meta-absorbers, where the electric field and power loss were mainly concentrated in the additional thin dielectric layer. Such a broadband THz absorption was achieved through electromagnetic coupling between the top and middle metal layers and the resultant overlapping of the resonance frequencies. This strategy can be adapted to other spectrum-shaping devices.

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