Adsorption techniques offer unique advantages owing to the use of synthetic (e.g., nanosized metal oxides and polymer-functionalized nanocomposites) and natural (e.g., clay and biochar) materials for pollutant removal. Although the most widely used adsorbent is activated carbon, extensive studies have highlighted the promising potential of modified clay minerals and biochar for removing heavy metal and organic pollutants from industrial, drinking, and eutrophic wastewater, due to their low cost and easy accessibility. However, clay modification using acids, calcination, polymers, or surfactants exhibits relatively low absorption/regeneration ability towards antibiotics, aromatics, and various dyes. The coexistence of numerous contaminants in industrial wastewater inhibited the performance of adsorbents, which accelerated the development of novel modified clay composites such as clay-biochar, organobentonite/sodium alginate beads, and enhanced biochar. This review summarizes recent studies and absorption mechanisms concerning clay composites based on various modification methods and component materials. The comparison of clay composites used for the removal of organic and inorganic contaminants provides valuable insight into real wastewater treatment. Knowledge gaps, uncertainties, and future challenges involved in the fabrication and regeneration of modified clay composites are also identified.
A facile green route has been employed for the synthesis of Zno and Ag-doped Zno using cannabis sativa as a reducing and stabilizing agent. the as-synthesized nanoparticles were characterized and tested for photocatalytic dye degradation and antimicrobial activity. the results suggested that nanoparticles have shown antimicrobial activity against different human pathogenic bacteria (Escherichia coli, Klebsiella pneumonia, MRSA, Pseudomonas aeruginosa, Salmonella typhi, Staphylococcus aureus) and fungal strains (Fusarium spp. and Rosellinia necatrix). Ag-doped nanoparticles comparatively have shown better removal congo red and methyl orange under visible light. Therefore, green synthesized nanoparticles could have beneficial applications in environmental science and biological field.
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