Carbon-silica composites with nanoporous structures were synthesized for the adsorption of volatile organic compounds (VOCs), taking tetraethyl orthosilicate (TEOS) as the silicon source and activated carbon powder as the carbon source. The preparation conditions were as follows: the pH of the reaction system was 5.5, the hydrophobic modification time was 50 h, and the dosage of activated carbon was 2 wt%. Infrared spectrum analysis showed that the activated carbon was dispersed in the pores of aerogel to form the carbon-silica composites material. The static adsorption experiments, dynamic adsorption-desorption experiments, and regeneration experiments show that the prepared carbon-silica composites have microporous and mesoporous structures, the adsorption capacity for n-hexane is better than that of conventional hydrophobic silica gel, and the desorption performance is better than that of activated carbon. It still has a high retention rate of adsorption capacity after multiple adsorption-desorption cycles. The prepared carbon-silica composites material has good industrial application prospects in oil vapor recovery, providing a new alternative for solving organic waste gas pollution.
Calculation process of some reservoir engineering problems involves several passes of full-order numerical reservoir simulations, and this makes it a time-consuming process. In this study, a fast method based on proper orthogonal decomposition (POD) was developed to predict flow and heat transfer of oil and water in a reservoir. The reduced order model for flow and heat transfer of oil and water in the hot water-drive reservoir was generated. Then, POD was used to extract a reduced set of POD basis functions from a series of “snapshots” obtained by a finite difference method (FDM), and these POD basis functions most efficiently represent the dynamic characteristics of the original physical system. After injection and production parameters are changed constantly, the POD basis functions combined with the reduced order model were used to predict the new physical fields. The POD-based method was approved on a two-dimensional hot water-drive reservoir model. For the example of this paper, compared with FDM, the prediction error of water saturation and temperature fields were less than 1.3% and 1.5%, respectively; what is more, it was quite fast, where the increase in calculation speed was more than 70 times.
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