Currently, morphology optimization methods for the fused‐ring nonfullerene acceptor‐based polymer solar cells (PSCs) empirically follow the treatments originally developed in fullerene‐based systems, being unable to meet the diverse molecular structures and strong crystallinity of the nonfullerene acceptors. Herein, a new and universal morphology controlling method is developed by applying volatilizable anthracene as solid additive. The strong crystallinity of anthracene offers the possibility to restrict the over aggregation of fused‐ring nonfullerene acceptor in the process of film formation. During the kinetic process of anthracene removal in the blend under thermal annealing, donor can imbed into the remaining space of anthracene in the acceptor matrix to form well‐developed nanoscale phase separation with bi‐continuous interpenetrating networks. Consequently, the treatment of anthracene additive enables the power conversion efficiency (PCE) of PM6:Y6‐based devices to 17.02%, which is a significant improvement with regard to the PCE of 15.60% for the reference device using conventional treatments. Moreover, this morphology controlling method exhibits general application in various active layer systems to achieve better photovoltaic performance. Particularly, a remarkable PCE of 17.51% is achieved in the ternary PTQ10:Y6:PC71BM‐based PSCs processed by anthracene additive. The morphology optimization strategy established in this work can offer unprecedented opportunities to build state‐of‐the‐art PSCs.
We derive an analytical formula to estimate the variance of nonlinear phase noise caused by the interaction of amplified spontaneous emission (ASE) noise with fiber nonlinearity such as self-phase modulation (SPM), cross-phase modulation (XPM), and four-wave mixing (FWM) in coherent orthogonal frequency division multiplexing (OFDM) systems. The analytical results agree very well with numerical simulations, enabling the study of the nonlinear penalties in long-haul coherent OFDM systems without extensive numerical simulation. Our results show that the nonlinear phase noise induced by FWM is significantly larger than that induced by SPM and XPM, which is in contrast to traditional WDM systems where ASE-FWM interaction is negligible in quasi-linear systems. We also found that fiber chromatic dispersion can reduce the nonlinear phase noise. The variance of the total phase noise increases linearly with the bit rate, and does not depend significantly on the number of subcarriers for systems with moderate fiber chromatic dispersion.
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