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Catalysts with high oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) performances are crucial to the development of lithium-oxygen batteries (LOBs), which aim to promote Li2O2 deposition and decomposition and then avoid the active site passivation. Considering the metallic Ag possessing good electrical conductivity and excellent catalytic activity and perovskite oxides exhibiting high abundance, an easily tunable structure, and excellent intrinsically catalytic activity, we adopt the ultraviolet light to realize the deposition of Ag nanoparticles on the La0.6Sr0.4Fe0.9Mn0.1O3 (LSFM) substrate as a high-performance cathode for LOBs. The results confirm that the synergetic effect of Ag nanoparticle decoration and the La0.6Sr0.4Fe0.9Mn0.1O3 substrate could dramatically improve the electronic conductivity and ORR/OER kinetics of the nanohybrids. Ag@LSFM hybrids with abundant active sites and considerable electronic conductivity promote the deposition of a thinner discharge product film, and the corresponding LOBs deliver high discharge capacity (12 477 mAh g–1), a small gap between charge and discharge potentials (∼1.3 V), and high cycling stability (147 cycles). Overall, the study suggests that such a bifunctional catalyst is a promising candidate in LOBs.

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