The rapidly rising demand for fiber-reinforced plastics (FRPs) has led to large volumes of manufacturing and end-of-life waste. Recycling fiber-reinforced thermosets is very difficult owing to their complex structure and heterogeneity. Landfill and incineration have become the most commonly used methods for eliminating non-degradable FRP waste, which adversely affects the environment and ecology. The purpose of this review is to evaluate end-of-life FRP recycling technologies in terms of optimizing the reuse/recycling of resources and eliminating waste, thereby improving FRP waste management. The technical progress made in the recycling of thermosetting composites is reviewed, including mechanical, thermal (pyrolysis and fluidized-bed), and chemical (critical fluid and low-temperature solvent) methods. The technical feasibility of each method was compared, and the economic and environmental impacts were considered. The challenges and opportunities facing the establishment of a composite recycling market in the future are examined. Finally, we provide a comprehensive summary of the scope of each recycling method.
The purpose of this study was to histologically and mechanically appraise the in vivo bone-bonding abilities of K2TinO2n+1 coated and uncoated Ti-15Mo-3Nb (TMN) implants. According to GB/T16886.6-1997 biological evaluation of medical devices Part 6:Tests for local effects after implantation, the two types of implants were implanted into the proximal metaphyses of Chinese white rabbits’ femurs for 12, 26 and 52 weeks and investigated by pushing out test, scanning electron microscopy (SEM) attached to an energy-dispersive X-ray micro-analyzer (EDX) and light microscopy. The bone-bonding abilities of the K2TinO2n+1 biocoating /Ti-15Mo-3Nb (KBT) gradient biomaterial implants were higher than those of T implants at different periods of implantation. The K2TinO2n+1 biocoating (KB) could stimulate new bone rapid formation at the early stages of implantation. And the implants with the biocoating eventually bonded to bone directly, with no intervening soft tissue layer, that was an osseocoalescence. However, the type of bone-bonding between TMN titanium alloy implants and bone was a simple osseocoaptation. The more excellent bone-bonding ability of the KBT implants should be attributed to the superficial characteristics, the bioactivity of low potassium titanate and biostability of high potassium titanate.
In this study, the load level, soil cover height, rise-span ratio, and arch foot constraint state were utilized to explore the mechanical properties of buried arch glass fiber reinforced plastics (GFRP) structures. Through the indoor scale-down test, the stress and deformation of arched GFRP structures under different load and soil cover height were investigated. Additionally, through the three-dimensional finite element method, the influence of the rise-span ratio and the constraint state of arch foot on the mechanical properties were obtained. The results indicate the new buried composite arch structure has excellent bearing capacity for the possible traffic load. Simultaneously, the semi-elliptical arch structure was believed to outperform the semi-circular arch structure when considering the external load. Specifically, increasing the soil cover height and reducing rise-span ratio were found to achieve the load-reduction effect.
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