Because of distinctive properties, such as dendritic structure, high green strength, and low oxygen content, electrolytic copper powder has been widely used in aviation, aerospace, national defense industry and other domains. But at present, energy consumption of the electrolysis process in copper powder production is high, and the current efficiency is only about 90%. Therefore,the decrease in energy consumption of the electrolysis process has become the major bottlenecks in the development of the enterprises. In this paper, a new electrolysis cell with different electrolyte inlet arranged on the cell was manufactured. Then, the effect of flow pattern of electrolyte on the current efficiency, energy consumption and properties of copper powder was investigated. The experimental results showed that the electrolytic process had the higher current efficiency, lower energy consumption and smaller copper powders when the flow rate is 0.5l/min in the paralleled inlet and 1.5 l/min in the traditional inlet. Under the optimal conditions, the current efficiency, energy consumption and copper powder size were 99.10%, 712.90kw∙h/t and 47.80um respectively. This means an obvious rise in current efficiency and decrease in energy consumption compared to traditional feeding method.
In the process of resource utilization of high phosphorus iron ores, phosphorus should be removed first. Compared to other dephosphorization methods, selective leaching with acid has special advantages such as high dephosphorization ratio, low iron loss and so on. However, a large amount of acidic wastewater containing phosphorus was produced after acid leaching. Therefore, the rational use of acidic wastewater and decrease of acid consumption is crucial to remove phosphorus by acid leaching. In this paper, the thermodynamics of the acid leaching was studied according to the existence form of mineral constituents in high phosphorus iron ores from Wushan Mountain. Then, crosscurrent acid leaching was employed to remove phosphorus from high phosphorus iron ores in Wushan Mountain and the changes in dephosphorization ratio, iron loss and acid concentration was observed during the leaching. The results showed that the phosphorus in Wushan iron ores could be removed selectively by acid leaching. After three-stage crosscurrent leaching, the dephosphorization ratio exceeded 74% and the iron loss was under 2.1%. Meanwhile, the acid concentration was decreased to 0.65mol/l in leaching solution, which could be returned to selective leaching after precipitation of phosphorus and supplement of hydrochloric acid.
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