Electrochromic
materials have great application in soft displays
and devices, but the application of ideal electrochromic textiles
still faces challenges owing to the inconvenience of a continuous
power supply. Here, electrochromic color-memory microcapsules (ECM-Ms-red,
-yellow, and -blue) with a low drive voltage (2.0 V), coloration efficiency
(921.6 cm2 C–1), a practical response
rate (34.4 s–1), multistage response discoloration,
and good color-memory performance (>72 h) and reversibility (≥1000
cycles) are developed. The color-memory performance is controlled
by the energy difference of oxidation–reduction reactions.
A multicolor and multistage response electrochromic color-memory wearable
smart textile and flexible display are developed that are convenient
and energy-efficient for application. The design philosophy of color-memory
based on controllable energy difference of reactions has great potential
application in sensors and smart textiles.
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