In recent years, high-mobility GaSb nanowires have received tremendous attention for high-performance p-type transistors; however, due to the difficulty in achieving thin and uniform nanowires (NWs), there is limited report until now addressing their diameter-dependent properties and their hole mobility limit in this important one-dimensional material system, where all these are essential information for the deployment of GaSb NWs in various applications. Here, by employing the newly developed surfactant-assisted chemical vapor deposition, high-quality and uniform GaSb NWs with controllable diameters, spanning from 16 to 70 nm, are successfully prepared, enabling the direct assessment of their growth orientation and hole mobility as a function of diameter while elucidating the role of sulfur surfactant and the interplay between surface and interface energies of NWs on their electrical properties. The sulfur passivation is found to efficiently stabilize the high-energy NW sidewalls of (111) and (311) in order to yield the thin NWs (i.e., <40 nm in diameters) with the dominant growth orientations of ⟨211⟩ and ⟨110⟩, whereas the thick NWs (i.e., >40 nm in diameters) would grow along the most energy-favorable close-packed planes with the orientation of ⟨111⟩, supported by the approximate atomic models. Importantly, through the reliable control of sulfur passivation, growth orientation and surface roughness, GaSb NWs with the peak hole mobility of ∼400 cm(2)V s(-1) for the diameter of 48 nm, approaching the theoretical limit under the hole concentration of ∼2.2 × 10(18) cm(-3), can be achieved for the first time. All these indicate their promising potency for utilizations in different technological domains.

High-quality CH 3 NH 3 PbI 3−x Cl x (MAPIC) films were prepared using potassium chloride (KCl) as an additive on indium tin oxide (ITO)-coated glass substrates using a simple one-step and low-temperature solution reaction. The Au/KCl-MAPIC/ITO/glass devices exhibited obvious multilevel resistive switching behavior, moderate endurance, and good retention performance. Electrical conduction analysis indicated that the resistive switching behavior of the KCl-doped MAPIC films was primarily attributed to the trap-controlled space-charge-limited current conduction that was caused by the iodine vacancies in the films. Moreover, the modulations of the barrier in the Au/KCl-MAPIC interface under bias voltages were thought to be responsible for the resistive switching in the carrier injection trapping/detrapping process.

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Inspired by the intelligent systems in nature, artificial systems with complicated practical functions have been developed for decades. The pathway toward the target is now based on the discoveries for new stimuli-responsive and freestanding materials to construct the advanced intelligent systems, instead of just electronic machines. Structural color materials, including both photonic crystalline and amorphous structures, are typical candidates due to the smart biomimetic characteristics, such as self-healing, autonomous regulation, and on-demand adaptability. However, to improve the stability and simplify the fabrication process of such materials, great efforts have been made in the modification of colloidal selfassembly techniques for more efficient real-life applications. A comprehensive review investigating various direct self-assembly techniques of colloids for the facile fabrication of structural color materials toward practical applications is provided. Recent advances of these self-assembly schemes of colloidal particles are presented, along with valuable design guidelines of these techniques to achieve efficient structural color materials for advanced intelligent systems.The ORCID identification number(s) for the author(s) of this article can be found under https://doi.