An enhancement strategy is realized for ultralong bright room-temperature phosphorescence (RTP), involving polymerization between phosphor monomers and acrylamide and host-guest complexation interaction between phosphors and cucurbit[6,7,8]urils (CB[6,7,8]). The non-phosphorescent monomers exhibit 2.46 su ltralong lifetime after copolymerizing with acrylamide.T he improvement is due to the rich hydrogen bond and carbonyl within the polymers which promote intersystem crossing, suppress nonradiative relaxation and shield quencherse ffectively.B yt uning the ratio of chromophores,aseries of phosphorescent copolymers with different lifetimes and quantum yields are prepared. The complexation of macrocyclic hosts CB[6,7,8] promote the RTP of polymers by blocking aggregation-caused quenching, and offsetting the losses of aforementioned interaction provided by polymer.M ultiple lifetime-encoding for digit and character encryption are achieved by utilizing the difference of their lifetimes.
Wastewater
treatment is in a dilemma: more energy and efforts have
to be put forth to obtain an effluent with better quality, while a
significant amount of sludge is generated and the treatment or disposal
expenses are high. Even if the sludge is disposed of properly, the
components can be released and pollute the environment again. Therefore,
conversion and recovery of the contaminants to resources is the way
out of the dilemma. An ion exchange membrane (IEM) is a special type
of membrane, which allows charged solutes to pass through it while
retaining uncharged components. Attributed to this character, IEMs
are taking more important roles in separation and conversion processes
recently. They act as key elements in many resource recovery systems,
such as in separation and concentration, salt valorization, energy
conversion, and even in microbial systems. This review summarizes
the important processes for waste conversion and resource recovery
from wastewaters by using IEMs. Drawbacks and perspectives are summarized
in view of the development of the processes and the membranes.
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