Lunar glasses are characterized by complex origin (i.e., volcanism or impact), compositional diversity (e.g., picritic, basaltic, or feldspathic), and visible/near‐infrared spectra similarity. This makes it is problematic to distinguish different types of lunar glasses in laboratory and remote data. In this study, we present micro‐FTIR (Fourier Transform Infrared) spectroscopy spectra (550–1450 cm–1) of a suite of lunar volcanic origin glasses (i.e., pyroclastic glasses) and impact‐generated glasses (i.e., mare and highland impact glasses), identified in lunar breccia meteorite Northwest Africa 7948. The results show that lunar pyroclastic glasses, mare impact glasses, and highland impact glasses exhibit different FTIR spectral characteristics: (1) the Christiansen Feature positions of pyroclastic glasses are generally at a longer wavelength (i.e., >~8.3 μm equivalent to <~1,205 cm–1) than the spectra of mare and highland impact‐generated glasses (i.e., <~8.3 μm equivalent to >~1,205 cm–1); (2) a relatively strong minor peak was distinctly observed at longer wavelength (~13.5–16.5 μm equivalent to ~600–750 cm–1) for highland impact glasses. Therefore, new supplementary FTIR diagnostic criteria were proposed to discern different types of lunar glasses. Our studies demonstrated that midinfrared spectra could provide an effective tool to non‐destructively and quickly distinguish lunar glasses in laboratory (e.g., for the future Chang'E‐5 returned soils).

The winonaites are primitive achondrites that are associated with IAB iron meteorites. They provide valuable insights into differentiation processes on asteroids in the early Solar System. However, there is still little understanding of the lithological diversity as well as the structure of the winonaite parent asteroid. In this work, we report the petrologic texture and mineralogy of a suite of winonaites (i.e., Northwest Africa (NWA) 725, NWA 6448, NWA 4024, Grove Mountains (GRV) 022890, GRV 021663, and Sahara (SAH) 02029) that exhibit a wide diversity of petrographic textures from primitive chondritic texture to coarse-grained equigranular texture. In particular, we recognized an unusual winonaite (SAH 02029) with a distinctive mineralogy and mineral chemistry (e.g., depleted in troilite, plagioclase contains melt inclusions, high plagioclase An values, and LREE-depleted clinopyroxene). The petrological and mineralogical features of SAH 02029 indicate that this meteorite has undergone silicate partial melting and may represent the residue of ~ 5-10 vol% partial melting. The textural and mineralogical diversity among winonaites suggests that the winonaite-IAB parent asteroid would have formed a four-layered structure during its evolution history: (1) surface layer consisting of precursor chondritic materials; (2) subsurface layer composed of diverse lithologies that experienced limited metamorphism and FeNi-FeS partial melting; (3) deep residues of silicate partial melting; and (4) interior layer consisting of incomplete differentiation metal pools. This conclusion enables us to establish constraints on the evolution history of winonaite-IAB parent body.