Cryogenic carbon dioxide capture by the desublimation method has the advantage of being contamination free and energy efficient under high concentration. Due to the difficulty of collecting solid CO2 after desublimation, this method has not been applied. In this paper, a visual experimental setup for carbon dioxide desublimation and sublimation on a low temperature surface is introduced in detail. The core part of the experimental set-up is a visual tube-in-tube counterflow heat exchanger consisting of a Pyrex glass tube with a larger diameter and a stainless-steel tube with a smaller diameter. The crystal growth and dissipation occur on the precooled outer surface of the inner tube, which is recorded by a camera. When carbon dioxide desublimates under different working conditions, such as temperature and supersaturation, the growth shape and growth rate of the solid are different. The thermal properties of the solid such as porosity, thermal conductivity and density are also different, leading to variations in the sublimation process and speed. Three distinct sublimation processes are discussed in this paper to provide guidance on the actual carbon capture process.
The ecological vulnerability evaluation index was established through Normalized Difference Vegetation Index (NDVI), Wetness (WET), Normalized Difference Build-up and Soil Index (NDBSI) and Land Surface Temperature (LST) indicators, comprehensively evaluate the ecological vulnerability of Zhongxian County of Chongqing in 2002, 2009, and 2016 by Principal Components Analysis (PCA), and analyze its spatio-temporal evolution. The vulnerability areas of five levels were calculated respectively, and the overall index of ecological vulnerability was also calculated. The index of remote sensing ecological index (RSEI) and Normalized Difference Vegetation Index decreased first and then increased; the Wetness index showed an upward trend; the Normalized Difference Build-up and Soil Index index increased first and then decreased; and the Land Surface Temperature index decreased. The ecological vulnerability body index (EVBI) shows a downward trend, and the incremental changes are mainly concentrated in the negligible vulnerability areas and light vulnerability area, while the medium vulnerability, strong vulnerability and extreme vulnerability area generally show a downward trend. Furthermore, the new increment of ecological vulnerability grade area concentrates on negligible vulnerability area and light vulnerability area from 2002 to 2016. In general, the ecological vulnerability gradually shifts to low vulnerability, and the ecological environment tends to develop healthily.
With the development of urbanization, a large number of village settlements have disappeared. As important carriers of ethnic and cultural heritage, village settlements are important for the continuation of folk culture and farming spirit. Building a regional ecological security pattern helps to protect the integrity of village settlements and promote the sustainable development of the Chinese nation. In this work, the importance of ecosystem services was first obtained by using the Integrated Valuation of Ecosystem Services and Tradeoffs model (In-VEST) and the revised universal soil loss equation model (RUSLE) to evaluate the regional ecosystem services in the southeastern region of Chongqing (SRC). Then, the ecological importance evaluation results were combined with the sensory evaluation results to derive ecological conservation importance areas and identify ecological source points in their high-value areas. Finally, the ecological corridors were obtained by the minimum cumulative resistance model (MCR). The regional ecological security pattern was constructed, i.e., the triangular protection area strategy of “one screen, one belt, and three cores”. The results show the following: the total area of ecological source sites larger than 20 km2 in SRC is 436.02 km2, accounting for 2.28% of the area of SRC. The largest ecological patch is 69.93 km2, accounting for 16.04% of the total area of ecological source sites. Thirteen ecological source sites were identified as follows: four in Youyang County, three in Shizhu County, three in Wulong County, and one in Pengshui County. There are 78 ecological corridors with a total length of 4832.82 km, including 32 important ecological corridors with a length of about 1544.53 km and 46 potential ecological corridors with a length of about 3288.29 km. Based on the minimum cumulative model constructed by eight resistance factors, the spatial variation of the ecological resistance surface was analyzed, showing a trend of being high in the west and central part and low in the surrounding area. There are one high-value area of the resistance surface of Wulong County Nature Reserve and one high-value area of ecological sensitivity that overlap to the extreme, and which should be given sufficient protection attention. The core protected areas consist of three mountains including the Qiyao Mountain Range, the Wuling Mountain Range, and the Wulong County Nature Reserve. The ecological security pattern in SRC based on the mode of “source–ecological corridor–ecological node” can identify important ecological function areas, providing scientific guidance for sustainable development and ecological security protection in the ethnic village settlements in China.
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