Kallmann syndrome has distinctive features on MRI. Magnetic resonance imaging may aid in the diagnosis of KS in patients with ambiguous clinical findings.
Transition-metal selenides (TMSs) have great potential
in the synthesis
of supercapacitor electrode materials due to their rich content and
high specific capacity. However, the aggregation phenomenon of TMS
materials in the process of charging and discharging will cause capacity
attenuation, which seriously affects the service life and practical
applications. Therefore, it is of great practical significance to
design simple and efficient synthesis strategies to overcome these
shortcomings. Hence, P-doped Cu3Se2 nanosheets
are loaded on vertically aligned Cu2S nanorod arrays to
synthesize CF/Cu2S@Cu3Se2/P nanocomposites
with a unique core–shell heterostructure. Notably, the Cu2S precursors can be rapidly converted into Cu3Se2 nanorod arrays in situ in just 30 min at room temperature.
The unique core–shell heterostructure effectively avoids the
aggregation phenomenon, and the doped P elements further enhance the
electrochemical properties of the electrode materials. Therefore,
the as-prepared CF/Cu2S@Cu3Se2/P
electrode exhibits a high areal capacitance of 5054 mF cm–2 (1099 C g–1) at 3 mA cm–2 and
still retains 90.2% capacitance after 10 000 galvanostatic
charge–discharge (GCD) cycles. The asymmetric supercapacitor
(ASC) device assembled from synthetic CF/Cu2S@Cu3Se2/P and activated carbon (AC) possesses an energy density
of 41.1 Wh kg–1 at a power density of 480.4 W kg–1. This work shows that the designed CF/Cu2S@Cu3Se2/P electrode has broad application
prospects in the field of electrochemical energy storage.
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